Journal Article10.1002/ADMA.201703663
Metal-Organic Frameworks as Platforms for Catalytic Applications.
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TL;DR: An overview of recent developments achieved in MOF catalysis, including heterogeneousCatalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided.
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Abstract: Metal-organic frameworks (MOFs), also called porous coordination polymers, represent a class of crystalline porous materials built from organic linkers and metal ions/clusters. The unique features of MOFs, including structural diversity and tailorability as well as high surface area, etc., enable them to be a highly versatile platform for potential applications in many fields. Herein, an overview of recent developments achieved in MOF catalysis, including heterogeneous catalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided. The active sites involved in the catalysts are particularly emphasized. The challenges, future trends, and prospects associated with MOFs and their related materials for catalysis are also discussed.
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Metal–organic framework‐supported hydroxyapatite (UiO‐66@HAp): an efficient catalyst for the microwave‐assisted transesterification of palm oil
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References
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
7.7K
Metal–Organic Framework Materials as Chemical Sensors
Lauren E. Kreno,Kirsty Leong,Omar K. Farha,Mark D. Allendorf,Richard P. Van Duyne,Joseph T. Hupp +5 more
TL;DR: The potential to computationally predict, with good accuracy, affinities of guests for host frameworks points to the prospect of routinely predesigning frameworks to deliver desired properties.
6.7K
Luminescent metal–organic frameworks for chemical sensing and explosive detection
TL;DR: This review intends to provide an update of work published since then and focuses on the photoluminescence properties of MOFs and their possible utility in chemical and biological sensing and detection.
3.9K
Metal-organic frameworks in biomedicine.
Patricia Horcajada,Ruxandra Gref,Tarek Baati,Phoebe K. Allan,Guillaume Maurin,Patrick Couvreur,Gérard Férey,Russell E. Morris,Christian Serre +8 more
TL;DR: Metal Organic Frameworks in Biomedicine Patricia Horcajada, Ruxandra Gref, Tarek Baati, Phoebe K. Allan, Guillaume Maurin, Patrick Couvreur, G erard F erey, Russell E. Morris, and Christian Serre.
3.8K