Luminescent Metal–Organic Frameworks
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TL;DR: This critical review discusses the origins of MOF luminosity, which include the linker, the coordinated metal ions, antenna effects, excimer and exciplex formation, and guest molecules.
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Abstract: Metal–organic frameworks (MOFs) display a wide range of luminescent behaviors resulting from the multifaceted nature of their structure. In this critical review we discuss the origins of MOF luminosity, which include the linker, the coordinated metal ions, antenna effects, excimer and exciplex formation, and guest molecules. The literature describing these effects is comprehensively surveyed, including a categorization of each report according to the type of luminescence observed. Finally, we discuss potential applications of luminescent MOFs. This review will be of interest to researchers and synthetic chemists attempting to design luminescent MOFs, and those engaged in the extension of MOFs to applications such as chemical, biological, and radiation detection, medical imaging, and electro-optical devices (141 references).
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Citations
Synthesis of sulfamic acid supported on Cr-MIL-101 as a heterogeneous acid catalyst and efficient adsorbent for methyl orange dye
TL;DR: In this paper, a modified MIL-101 was characterized by XRD, TEM, SEM and FT-IR measurements, and the results indicated that the adsorption capacity was modified by changing the amount of sulfamic acid loaded on MIL- 101.
Colorimetric determination of Cu(II) ions in biological samples using metal-organic framework as scaffold
TL;DR: In this article, a novel optical chemo-sensor for visual detection of Cu(II) ions in the water and biological samples is developed, which is based on the use of metal-organic frameworks (UiO-66).
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Multifunctional Metal–Organic Frameworks Based on Redox-Active Rhenium Octahedral Clusters
Yulia M. Litvinova,Yakov M. Gayfulin,Konstantin A. Kovalenko,Konstantin A. Kovalenko,Denis G. Samsonenko,Denis G. Samsonenko,Jan van Leusen,Ilya V. Korolkov,Ilya V. Korolkov,Vladimir P. Fedin,Vladimir P. Fedin,Yuri V. Mironov,Yuri V. Mironov +12 more
TL;DR: The redox-active rhenium octahedral cluster unit [Re6Se8(CN)6]4- was combined with Gd3+ ions and dicarboxylate linkers in novel types of metal-organic frameworks (MOFs) that display a set of functional properties and demonstrate an ability for reversible redox transformations of the cluster fragment.
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A metal-organic framework based multifunctional catalytic platform for organic transformation and environmental remediation.
TL;DR: The iodine incorporated MOF showed tremendous efficiency in organic catalysis for the synthesis of a library of benzimidazole derivatives with yield >80% and established its efficacy as a multifunctional catalyst in the organic synthesis of biologically active motifs and photocatalytic dye degradation.
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Ten Coordination Polymers Constructed Using an Unprecedented Azamacrocyclic Octacarboxylate Ligand 1,4,8,11-Tetrazacyclododecane-N,N′,N″,N‴-Tetra-Methylene-Isophthalic Acid: Syntheses, Structures, and Photoluminescent Properties
TL;DR: In this article, the structure of coordination complexes has been characterized by relative physical methods, and a number of new coordination complexes have been synthesized, such as [Cd3(H2L)(H2O)7]·6H 2O (1), [Mn3(h2L), H2O (2), [Ni3(L)(teta)4(H 2 O)6], [Ni4(L), Ni3(T), H 2 O (4,6), [Fe3(Fe3,H 2.
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Lanthanide luminescence for functional materials and bio-sciences
TL;DR: This critical review describes the latest developments in the sensitization of near-infrared luminescence, "soft" luminescent materials (liquid crystals, ionic liquids, ionogels), electroluminescentmaterials for organic light emitting diodes, with emphasis on white light generation, and applications in luminecent bio-sensing and bio-imaging based on time-resolved detection and multiphoton excitation.