Patent
Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils
N. Hans Van Toor,Gijsbertus Johannes Van Rossum,Marco Kruidenberg +2 more
- 30 Jul 2004
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TL;DR: In this paper, the authors present low trans-fatty acid fat compositions, methods of hydrogenating unsaturated feedstocks (e.g., oils), and hydrogenation catalyst compositions.
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Abstract: The present disclosure provides low trans-fatty acid fat compositions, methods of hydrogenating unsaturated feedstocks (e.g., oils), and hydrogenation catalyst compositions. One exemplary method involves producing a catalyst composition by heating a nickel-based catalyst to a first temperature of at least about 85° C in the presence of hydrogen and a fat component. An unsaturated feedstock may be contacted with the catalyst composition and hydrogenated by sustaining a hydrogenation reaction at a second temperature of no greater than about 700 C. Some specific implementations of the invention permit the production of partially hydrogenated seed oils with low trans-fatty acid contents.
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Citations
Recent Progress in Synthesis of Fine and Specialty Chemicals from Wood and Other Biomass by Heterogeneous Catalytic Processes
TL;DR: In this paper, the synthesis of fine and specialty chemicals involving heterogeneous catalysts is discussed according to the type of reactions (e.g., hydrogenation, oxidation, isomerization, etc.) for various biomass derived feedstocks.
303
Patent
Synthesis of terminal alkenes from internal alkenes via olefin metathesis
Yann Schrodi,Richard L. Pederson,Hiroki Kaido,Michael J. Tupy +3 more
- 15 Oct 2007
TL;DR: In this article, a method for synthesizing terminal olefin from internal alkenes using a cross-metathesis reaction catalyzed by an olefins metathesis catalyst is described.
140
Patent
Compositions comprising metathesized unsaturated polyol esters
Diza Pearl Braksmayer,Timothy A. Murphy,Stephen E. Russell,Michael John Tupy,Scott Walters +4 more
- 07 Mar 2007
TL;DR: In this paper, the petrolatum-like compositions that comprise metathesized unsaturated polyol esters are discussed and the emulsions may be used as substitutes for petroleum-based petrolatum.
84
Patent
Methods of Making Organic Compounds by Metathesis
Timothy W. Abraham,Hiroki Kaido,Choon Woo Lee,Richard L. Pederson,Yann Schrodi,Michael J. Tupy +5 more
- 10 Apr 2009
TL;DR: In this article, a cross-metathesis step with an olefin compound is used to produce functionalized alkene intermediates having a pre-determined double bond position.
78
Patent
Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
Yann Schrodi
- 13 Jul 2007
TL;DR: In this paper, a method for synthesizing terminal alkenes from internal olefin with a selected metathesis catalyst has been described, which has utility in the fields of catalysis, organic synthesis, and industrial chemistry.
77
References
Patent
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Orus F Krumboltz
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Patent
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Patent
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Patent
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Leslie G Jenness
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TL;DR: In this paper, a method for selectively hydrogenating glyceride oils which contain substantial quantities of fatty acid radicals having more than double bonds to produce products having improved keeping qualities was proposed.
7
Novel method of edible oil hydrogenation, 3: Soybean oil hydrogenation using hydrogen storage alloy
TL;DR: LaNi4.0 Al1.1.0 as mentioned in this paper LaNi5.0 LaNi3.0Al1.2 LaNi2.0.1 LaNi6.
7