Journal Article10.1038/S41578-018-0054-3
Liquid, glass and amorphous solid states of coordination polymers and metal–organic frameworks
Thomas D. Bennett,Satoshi Horike +1 more
384
TL;DR: A review of the structural design, properties and potential applications of non-crystalline coordination polymers and metal-organic frameworks can be found in this paper, where the authors discuss the background and terminology of this emerging field, categorize example structures and provide an outlook for the future direction of the field.
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Abstract: The field of coordination polymers and metal–organic frameworks has to date focused on the crystalline state. More than 60,000 crystalline metal–organic framework structures, formed from highly ordered arrays of metal nodes connected by organic ligands in at least one dimension, have been identified. However, interest in non-crystalline systems is growing, with amorphous solids, glasses and liquids identified as possessing similar metal–ligand bonding motifs to their crystalline cousins. In this Review, we provide an overview of the structural design, properties and potential applications of non-crystalline coordination polymers and metal–organic frameworks. In particular, we highlight recent reports of glasses that result from the melt quenching of the liquid states of these topical classes of materials. Finally, we provide a perspective on the future of the non-crystalline domain of coordination polymers and metal–organic frameworks. There is increasing interest in the liquid, glass and amorphous solid states of coordination polymers and metal–organic frameworks. In this Review, we discuss the background and terminology of this emerging field, categorize example structures and provide an outlook for the future direction of the field.
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References
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
14K
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Kyo Sung Park,Zheng Ni,Adrien P. Côté,Jae Yong Choi,Rudan Huang,Fernando J. Uribe-Romo,Hee K. Chae,Michael O'Keeffe,Omar M. Yaghi +8 more
TL;DR: Study of the gas adsorption and thermal and chemical stability of two prototypical members, ZIF-8 and -11, demonstrated their permanent porosity, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvents.
6.6K
A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability.
Jasmina Hafizovic Cavka,Søren Jakobsen,Unni Olsbye,Nathalie Guillou,Carlo Lamberti,Silvia Bordiga,Karl Petter Lillerud +6 more
TL;DR: The Zr-MOFs presented in this work have the toughness needed for industrial applications; decomposition temperature above 500 degrees C and resistance to most chemicals, and they remain crystalline even after exposure to 10 tons/cm2 of external pressure.
6.2K
Formation of glasses from liquids and biopolymers.
TL;DR: The onset of a sharp change in ddT( is the Debye-Waller factor and T is temperature) in proteins, which is controversially indentified with the glass transition in liquids, is shown to be general for glass formers and observable in computer simulations of strong and fragile ionic liquids, where it proves to be close to the experimental glass transition temperature.
4.7K
Supercooled liquids and the glass transition
TL;DR: Current theoretical knowledge of the manner in which intermolecular forces give rise to complex behaviour in supercooled liquids and glasses is discussed.
4.6K