Journal Article10.1016/S0010-8545(99)00253-2
Ligand-centered reactivity of organometallic radicals
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TL;DR: A review of ligand-centered reactions of organometallic radicals with emphasis on the recent literature is given in this paper, where the focus is on metal-centered reactivity.
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About: This article is published in Coordination Chemistry Reviews. The article was published on 01 Sep 2000. The article focuses on the topics: Reactivity (chemistry).
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Citations
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Redox Noninnocence of Carbene Ligands: Carbene Radicals in (Catalytic) C−C Bond Formation
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Palladium-catalyzed oxidative ethoxycarbonylation of aromatic C-H bond with diethyl azodicarboxylate.
TL;DR: This communication describes the Pd(OAc)2-catalyzed ethoxycarbonylation reactions of aromatic C−H bonds using diethyl azodicarboxylate (DEAD) together with Oxone or K2S2O8.
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Regiospecific synthesis of nitroarenes by palladium-catalyzed nitrogen-donor-directed aromatic C-H nitration.
TL;DR: The first example of palladium-catalyzed direct ortho-nitration of aryl C-H bonds was presented in this paper, where the first example was based on the first-order orthogonality.
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Radical Coordination Chemistry and Its Relevance to Metal‐Mediated Radical Polymerization
TL;DR: The reactions engaged by organic radicals with transition metal complexes are reviewed in this article with a particular focus on how they can interplay with and affect the results of radical polymerization, and various ways in which metal complexes can play a role in radical polymers.
References
Organometallic molecular wires and other nanoscale-sized devices: An approach using the organoiron (dppe)Cp*Fe building block
Frédéric Paul,Claude Lapinte +1 more
TL;DR: In this article, the potential that organometallic architectures consisting of two transition metal centers linked by an organic unsaturated spacer present for the study and development of new molecular wires is discussed.
591
Selective Generation of Free Radicals from Epoxides Using a Transition-Metal Radical. A Powerful New Tool for Organic Synthesis
TL;DR: Bis(cycIopentadienyl)titanium(III) chloride reacts with epoxides by initial C-0 homolysis and the regiochemistry of the opening is determined by the relative stabilities of the radicals as discussed by the authors.
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