Interfacial built-in electric-field for boosting energy conversion electrocatalysis.
Hui-Lin Xu,Junru Li,Xianxu Chu +2 more
TL;DR: In this article , a critical review regarding the concept, modulation strategies, and applications of BIEFs is comprehensively summarized, which begins with the fundamental concepts, together with the advantages of the BIEF for boosting electrocatalytic reactions.
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Abstract: The formation of a built-in electric field (BIEF) can induce electron-rich and electron-poor counterparts to synergistically modify electronic configurations and optimize the binding strengths with intermediates, thereby leading to outstanding electrocatalytic performance. Herein, a critical review regarding the concept, modulation strategies, and applications of BIEFs is comprehensively summarized, which begins with the fundamental concepts, together with the advantages of BIEF for boosting electrocatalytic reactions. Then, a systematic summary of the advanced strategies for the modulation of BIEF along with the in-detail mechanisms in its formation are also added. Finally, the applications of BIEF in driving electrocatalytic reactions and some cascade systems for illustrating the conclusive role from the induced BIEF are also systematically discussed, followed by perspectives on the future deployment and opportunity of the BIEF design.
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References
Single-boron catalysts for nitrogen reduction reaction
Chuangwei Liu,Qinye Li,Chengzhang Wu,Jie Zhang,Yonggang Jin,Douglas R. MacFarlane,Chenghua Sun +6 more
TL;DR: Single boron atoms supported on graphene and substituted into h-MoS2 are identified as the most promising NRR catalysts, offering excellent energy efficiency and selectivity against hydrogen evolution reaction.
572
Se-Doping Activates FeOOH for Cost-Effective and Efficient Electrochemical Water Oxidation.
TL;DR: Theoretical analysis and systematic experiments prove that Se-doping enables FeOOH as an efficient and low-cost OER electrocatalyst and develop a facile on-site electrochemical activation strategy for achieving such a Se- doped FeOOh electrode via an FeSe precatalyst.
557
Ultrahigh-Loading of Ir Single Atoms on NiO Matrix to Dramatically Enhance Oxygen Evolution Reaction.
TL;DR: Density functional theory calculations reveal that the substituted single Ir atom not only serves as the active site for OER but also activates the surface reactivity of NiO, which thus leads to the dramatically improved OER performance.
541
Sodium-Decorated Amorphous/Crystalline RuO2 with Rich Oxygen Vacancies: A Robust pH-Universal Oxygen Evolution Electrocatalyst
Lijie Zhang,Haeseong Jang,Huihui Liu,Min Gyu Kim,Dongjiang Yang,Shangguo Liu,Xien Liu,Jaephil Cho +7 more
TL;DR: In this paper, a pH-universal OER electrocatalyst, a/c-RuO 2, was developed as a pH universal OER catalysts, which showed remarkable resistance to acid corrosion and oxidation during OER, which leads to an extremely high catalytic stability.
453
Metal-Organic Frameworks Derived Functional Materials for Electrochemical Energy Storage and Conversion: A Mini Review
TL;DR: In this paper, metal-organic frameworks (MOFs) have been identified as versatile precursors or sacrificial templates for preparing functional materials as advanced electrodes or high-efficiency catalysts for electrochemical energy storage and conversion (EESC).
429