Journal Article10.1021/OM200534M
Impact of Cyclometalation and π-Conjugation on Photoisomerization of an N,C-Chelate Organoboron Compound
Ying-Li Rao,Suning Wang +1 more
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TL;DR: N,C-Chelate four-coordinate boron compounds that contain a B(ppy)Mes2 unit (ppy = 2phenylpyridyl, Mes = mesityl) are a new class of photochromic molecules discovered recently by.
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About: This article is published in Organometallics. The article was published on 20 Jul 2011. The article focuses on the topics: Photoisomerization.
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Citations
Four-coordinate organoboron compounds for organic light-emitting diodes (OLEDs).
TL;DR: An overview of the progress in the molecular construction of four-coordinate organoboron compounds with an emphasis on their applications in OLEDs is provided.
504
Application of the five-membered ring blue light-emitting iridium products of cyclometalation reactions as OLEDs
TL;DR: In particular, the presence of a high field ligand such as an N -heterocyclic carbene in these compounds facilitates high energy emission, which results in the desired blue-colored light required for OLED applications as mentioned in this paper.
114
Direct and Base-Catalyzed Diboration of Alkynes Using the Unsymmetrical Diborane(4), pinB-BMes2
TL;DR: In the absence of transition metal catalysts, the unsymmetrical diborane(4), pinB-BMes2, reacted with alkynes to afford diborylalkenes and this reaction could furthermore be applied to synthesize a luminescent molecule.
79
Organoboron-Based Photochromic Copolymers for Erasable Writing and Patterning
TL;DR: In this paper, the first examples of organoboron-based photochromic polymers are reported, which display thermally reversible photochromism, switching color from colorless to deep blue, and fluorescence from bright sky blue to deep green.
63
Blue phosphorescent N-heterocyclic carbene chelated Pt(II) complexes with an α-duryl-β-diketonato ancillary ligand
TL;DR: A single-crystal X-ray diffraction analysis revealed that the presence of the α-duryl-β-diketonato ligand in the Pt(II) compounds effectively suppresses the dimer formation in the crystal lattice.
48
References
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Polymorphism and Reversible Mechanochromic Luminescence for Solid-State Difluoroboron Avobenzone
TL;DR: A simple boron complex of a commercial sunscreen product exhibits morphology-dependent emission and mechanochromic luminescence in the solid state and in the rubbed regions, the fluorescence recovers slowly at room temperature or much faster with heating, resulting in a simple rewritable "scratch the surface" ink of potential commercial use.
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