Journal Article10.1039/B802256A
Hydrogen storage in metal–organic frameworks
TL;DR: This critical review of the current status of hydrogen storage within microporous metal-organic frameworks provides an overview of the relationships between structural features and the enthalpy of hydrogen adsorption, spectroscopic methods for probing framework-H(2) interactions, and strategies for improving storage capacity.
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Abstract: New materials capable of storing hydrogen at high gravimetric and volumetric densities are required if hydrogen is to be widely employed as a clean alternative to hydrocarbon fuels in cars and other mobile applications. With exceptionally high surface areas and chemically-tunable structures, microporous metal–organic frameworks have recently emerged as some of the most promising candidate materials. In this critical review we provide an overview of the current status of hydrogen storage within such compounds. Particular emphasis is given to the relationships between structural features and the enthalpy of hydrogen adsorption, spectroscopic methods for probing framework–H2 interactions, and strategies for improving storage capacity (188 references).
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References
An Accurate and Transferable Intermolecular Diatomic Hydrogen Potential for Condensed Phase Simulation.
TL;DR: An anisotropic many-body H2 potential energy function has been developed for use in heterogeneous systems and validated on dense supercritical hydrogen and demonstrated to reproduce the experimental data with high accuracy.
Interaction of Hydrogen with MOF-5
Silvia Bordiga,Jenny G. Vitillo,Gabriele Ricchiardi,Laura Regli,Donato Cocina,Adriano Zecchina,Bjørnar Arstad,Morten Bjørgen,Jasmina Hafizovic,Karl Petter Lillerud +9 more
TL;DR: The IR spectroscopy of adsorbed H2 performed at 15 K and ab initio calculations show that the adsorptive properties of this material are mainly due to dispersive interactions with the internal wall structure and to weak electrostatic forces associated with O13Zn4 clusters.
Broadly Hysteretic H2 Adsorption in the Microporous Metal−Organic Framework Co(1,4-benzenedipyrazolate)
TL;DR: X-ray powder diffraction data indicates that 1d possesses a substantially different structure, but converts back to 1 upon exposure to DEF, consistent with the presence of a flexible framework, and variable-temperature kinetics measurements have allowed the first study of H2 diffusion within a metal-organic framework.
Adsorption and diffusion of hydrogen in a new metal-organic framework material: [Zn(bdc)(ted)0.5]
Jinchen Liu,Jeong Yong Lee,Long Pan,R. T. Obermyer,S. Simizu,Brian Zande,Jing Li,S. G. Sankar,J. Karl Johnson +8 more
TL;DR: In this article, the authors have experimentally measured hydrogen isotherms at 77 and 298 K up to a hydrogen pressure of 50 bar in a recently developed metal-organic framework material, [Zn(bdc)(ted)0.5] (bdc = benzenedicarboxylate, ted = triethylenediamine).