Journal Article10.1021/OM980141Y
Hydride and Dihydrogen Ruthenium Complexes of the Tripyrrolylphosphine Ligand
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TL;DR: The reactivity of the ruthenium(IV) trihydride complex Cp*RuH3(Ppyl3) (2) has been studied with regard to substitution and protonation reactions as discussed by the authors.
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About: This article is published in Organometallics. The article was published on 31 Jul 1998. The article focuses on the topics: Dihydrogen complex & Ruthenium.
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Citations
Catalytic Hydrodefluorination of Aromatic Fluorocarbons by Ruthenium N-Heterocyclic Carbene Complexes
TL;DR: The catalytic reactions reveal a novel selectivity for substitution at the 2-position in C(6)F(5)H and C(5), and a first-order dependence on [fluoroarene] and zero-order relationship with respect to [R(3)SiH].
146
Ruthenium catalysed C-H bond borylation.
TL;DR: A novel ruthenium(iv)-catalysed C-H activation borylation/functionalization reaction using a remarkably low catalyst loadings is described.
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Syntheses and X-ray Diffraction Studies of Half-Sandwich Hydridosilyl Complexes of Ruthenium
TL;DR: The reactions of a series of half-sandwich trihydrides of ruthenium, Cp*(R3P)Ru(H)3 with a family of chlorosilanes (ClSiHMe2, Cl2SiMe, Cl3SiH) have been st...
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References
η2 Coordination of Si–H σ Bonds to Transition Metals
TL;DR: The first structural evidence for an Si-H interaction in complexes of the type Cp(OC) 2 Mn(H)SiR 3 was obtained for the SiPh 3 derivative as mentioned in this paper.
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Dihydrogen complexes of ruthenium. 2. Kinetic and thermodynamic considerations affecting product distribution
TL;DR: In this paper, it was shown that carbonyl free dihydrogen complexes of the form (({eta}-C{sub 5}H{sub 3} ) can be identified by observing substantial H-D coupling (22-32 Hz) in the {sup 1}H NMR spectra of the Hd analogues of the corresponding deuterides.
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