Journal Article10.1126/SCIENCE.1152516
High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture.
Rahul Banerjee,Anh Phan,Bo Wang,Carolyn B. Knobler,Hiroyasu Furukawa,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Members of a selection of zeolitic imidazolate frameworks have high thermal stability and chemical stability in refluxing organic and aqueous media, and they exhibit unusual selectivity for CO2 capture from CO2/CO mixtures and extraordinary capacity for storing CO2.
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Abstract: A high-throughput protocol was developed for the synthesis of zeolitic imidazolate frameworks (ZIFs). Twenty-five different ZIF crystals were synthesized from only 9600 microreactions of either zinc(II)/cobalt(II) and imidazolate/imidazolate-type linkers. All of the ZIF structures have tetrahedral frameworks: 10 of which have two different links (heterolinks), 16 of which are previously unobserved compositions and structures, and 5 of which have topologies as yet unobserved in zeolites. Members of a selection of these ZIFs (termed ZIF-68, ZIF-69, and ZIF-70) have high thermal stability (up to 390°C) and chemical stability in refluxing organic and aqueous media. Their frameworks have high porosity (with surface areas up to 1970 square meters per gram), and they exhibit unusual selectivity for CO 2 capture from CO 2 /CO mixtures and extraordinary capacity for storing CO 2 : 1 liter of ZIF-69 can hold ∼83 liters of CO 2 at 273 kelvin under ambient pressure.
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Citations
Structure and Properties of an Amorphous Metal-Organic Framework
Thomas D. Bennett,Andrew L. Goodwin,Andrew L. Goodwin,Martin T. Dove,David A. Keen,David A. Keen,Matthew G. Tucker,Emma R. Barney,Alan K. Soper,Erica G. Bithell,Jin-Chong Tan,Anthony K. Cheetham +11 more
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References
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
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High-throughput synthesis and catalytic properties of a molecular sieve with 18- and 10-member rings
TL;DR: The structure and catalytic activity of the silicogermanate zeolite ITQ-33 is reported, which exhibits straight large pore channels with circular openings of 18-rings along the c axis interconnected by a bidirectional system of 10-ring channels, yielding a structure with very large micropore volume.
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