Journal Article10.1126/SCIENCE.1152516
High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture.
Rahul Banerjee,Anh Phan,Bo Wang,Carolyn B. Knobler,Hiroyasu Furukawa,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Members of a selection of zeolitic imidazolate frameworks have high thermal stability and chemical stability in refluxing organic and aqueous media, and they exhibit unusual selectivity for CO2 capture from CO2/CO mixtures and extraordinary capacity for storing CO2.
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Abstract: A high-throughput protocol was developed for the synthesis of zeolitic imidazolate frameworks (ZIFs). Twenty-five different ZIF crystals were synthesized from only 9600 microreactions of either zinc(II)/cobalt(II) and imidazolate/imidazolate-type linkers. All of the ZIF structures have tetrahedral frameworks: 10 of which have two different links (heterolinks), 16 of which are previously unobserved compositions and structures, and 5 of which have topologies as yet unobserved in zeolites. Members of a selection of these ZIFs (termed ZIF-68, ZIF-69, and ZIF-70) have high thermal stability (up to 390°C) and chemical stability in refluxing organic and aqueous media. Their frameworks have high porosity (with surface areas up to 1970 square meters per gram), and they exhibit unusual selectivity for CO 2 capture from CO 2 /CO mixtures and extraordinary capacity for storing CO 2 : 1 liter of ZIF-69 can hold ∼83 liters of CO 2 at 273 kelvin under ambient pressure.
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Citations
What makes zeolitic imidazolate frameworks hydrophobic or hydrophilic? The impact of geometry and functionalization on water adsorption
TL;DR: It is shown that adequate functionalization of the linkers allows one to tune the host-guest interactions, even featuring dual amphiphilic materials whose pore space features both hydrophobic and hydrophilic regions.
140
Porous purple glass – a cobalt imidazolate glass with accessible porosity from a meltable cobalt imidazolate framework
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