Heterogeneous catalyst process

TL;DR: In this article, the use of heterogeneous (organic polymer-supported) calcium-containing catalysts and the use thereof in the preparation of alkoxylation products was discussed, i.e., condensation reaction products of alkylene oxides and organic compounds having at least one active hydrogen.

TL;DR: In this paper, the reaction is performed in the presence of diluents such as liquid saturated aliphatic or cycloaliphatic hydrocarbons, C 5 -C 16 alkenes of formula R 1 -CH═CH 2 or R 2 -CH--R 3, C 5 to C 12 cycloalkenes, which contain no branching on the C═C-bond, excess isobutene or mixtures thereof, at temperatures of 0° C. to 80° C., pressures of 0.1 to 11 bars and catalyst amounts of

TL;DR: In this article, an improved, environmentally safe DTBP was developed, which does not have the disadvantages mentioned and moreover produces good yields, starting from 2-TBP, the reaction with isobutene being carried out in the liquid phase, catalysed by aluminium tris-(2-tert.-butylphenolate), in the presence of fairly large amounts of saturated (cyclo)aliphatic hydrocarbons which are liquid under the reaction conditions and/or C5-C16-alkenes of the formulae R1-CH=CH2

TL;DR: In this paper, the authors describe a process for carrying out a reactive distillation in the presence of a heterogeneous catalyst which is suspended as a disperse phase in the liquid, wherein part of the catalyst-containing suspension is continuously discharged from the column and is treated in a work-up stage and at least part of a workup catalyst is returned to the column.

TL;DR: In this article, a process for the production of oxygenated compounds, more specifically aldehydes and alcohols, by reacting an olefin with hydrogen and carbon monoxide in the presence of, as a catalyst, an insoluble polymer containing a functional group, which may be an amine, thiol, phosphine, or arsine group, having chemically bonded to a metal of Group VIII of the Periodic Table.

TL;DR: In this article, the authors describe a POROUS METAL-ION-CHAIN-BRIDged POLYMERIC product with surface area of at least 5 M.2/G.