Journal Article10.1039/C1CS15279C
Gold catalysis in total synthesis—an update
958
TL;DR: In this critical review, the strongly increasing amount of new applications of gold catalysis in total synthesis is summarised and, for the new developed methods, the mode of activation of the substrate by the gold catalyst is discussed.
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Abstract: In this critical review, the strongly increasing amount of new applications of gold catalysis in total synthesis is summarised and, for the new developed methods, the mode of activation of the substrate by the gold catalyst is discussed (47 references).
read more
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Citations
Catalytic Activity of Cationic and Neutral Silver(I)–XPhos Complexes with Nitrogen Ligands or Tolylsulfonate for Mannich and Aza‐Diels–Alder Coupling Reactions
TL;DR: The isolation of new silver(I)-L complexes with reagents as ligands lends support to mechanistic proposals for such catalytic processes and the activity, stability and metal-distal arene interaction of these silver( I)-L catalysts have been compared with those of analogous cationic gold(I) and copper( I) complexes.
22
Gold-based nanoalloys: synthetic methods and catalytic applications
Pengyi Lu,Jingwen Zhou,Yukun Hu,Jinwen Yin,Yunhao Wang,Jinli Yu,Yangbo Ma,Zonglong Zhu,Zhiyuan Zeng,Zhanxi Fan +9 more
TL;DR: A review of gold-based nanoalloys can be found in this paper, where the general relationship between material structures/compositions and catalytic performances are discussed in representative chemical reactions, such as CO2RR, ORR, HER, oxygen evolution reaction (OER), small organic molecule oxidation reaction, carbon monoxide oxidation reaction in chemical engineering.
Efficient Gold(I) Acyclic Diaminocarbenes for the Synthesis of Propargylamines and Indolizines.
Mélanie Aliaga-Lavrijsen,Raquel P. Herrera,M. Dolores Villacampa,M. Concepción Gimeno +3 more
- 23 Aug 2018
TL;DR: The new gold(I) metal complexes are highly efficient catalysts for the synthesis of propargylamines and indolizines in the absence of solvent and in mild conditions and affords the corresponding final products with excellent yields in short reaction times.
Gold(I)‐Catalyzed Selective Heterocyclization of Propargylic Thioureas: Mechanistic Study of Competitive Gold‐Activation Mode
TL;DR: A new selective gold(I)-catalyzed intramolecular heterocyclization of propargylic thioureas has been developed, efficiently affording two kinds of cycloadducts in moderate to excellent yields with a broad substrate scope.
22
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