Journal Article10.1063/1.1136443
Fabry–Perot cavity pulsed Fourier transform microwave spectrometer with a pulsed nozzle particle source
T. J. Balle,W. H. Flygare +1 more
1.4K
TL;DR: In this article, the design, construction, and operation of a new type of microwave spectrograph which allows the measurement of the resonant transitions of transient or otherwise short-lived species is described.
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Abstract: We describe the design, construction, and operation of a new type of microwave spectrograph which allows the measurement of the resonant transitions of transient or otherwise short‐lived species. The spectrograph is composed of three parts: a Fabry–Perot cavity, a pulsed supersonic nozzle as a source for the sample, and the pulsed microwave Fourier transform method. Following a detailed discussion of the three above components in the spectrograph, the operation of the entire system is described and several examples are given.
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Citations
Spectroscopic characterization of C7H3(+) and C7H3˙: electronic absorption and fluorescence in 6 K neon matrices.
TL;DR: Comparison of the calculated harmonic vibrational frequencies with those inferred from the spectra supports the assignment of C7H3(+) as neutral radicals based on calculated vertical excitation energies using the CASPT2 method.
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Microwave measurements of cobalt and nitrogen quadrupole coupling in Co(CO)3NO
TL;DR: In this article, a Flygare-Balle type pulsed beam microwave spectrometer was used to measure the top molecule cobalt tricarbonyl nitrosyl.
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On the violation of Legon–Millen's rules for predicting angular geometries of hydrogen-bonded dimers: an ab initio study
TL;DR: In this article, the potential energy surfaces of furan, HCl, ClF, thiophene, and ClF complexes were extensively explored at the MP2/aug-cc-pVDZ level.
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Discriminating the structure of exo-2-aminonorbornane using nuclear quadrupole coupling interactions.
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TL;DR: The intrinsic conformational and structural properties of the bicycle exo-2-aminonorbornane have been probed in a supersonic jet expansion using Fourier-transform microwave (FT-MW) spectroscopy and quantum chemical calculations.
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Conformational analysis of n-butanal by Chirped-Pulse Fourier Transform Microwave spectroscopy
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References
Laser Beams and Resonators
H. Kogelnik,Tingye Li +1 more
TL;DR: This paper is a review of the theory-of laser beams and resonators and emphasis is placed on formulations and derivations which lead to basic understanding and on results which bear practical significance.
3.3K
Laser beams and resonators
H. Kogelnik,Tingye Li +1 more
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TL;DR: This paper is a review of the theory of laser beams and resonators and emphasis is placed on formulations and derivations which lead to basic understanding and on results which bear practical significance.
Resonant modes in a maser interferometer
A. G. Fox,Tingye Li +1 more
TL;DR: In this paper, a theoretical investigation has been undertaken to study diffraction of electromagnetic waves in Fabry-Perot interferometers when they are used as resonators in optical masers.
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Cluster Formation in Expanding Supersonic Jets: Effect of Pressure, Temperature, Nozzle Size, and Test Gas
O. F. Hagena,W. Obert +1 more
TL;DR: In this article, the authors used a retarding potential system to get the mass-to-charge distribution of the cluster ions and measured the size of the clusters with a through-flow ionization detector.
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