Journal Article10.1016/1010-6030(93)80157-5
Excited-state proton transfer reactions I. Fundamentals and intermolecular reactions
547
TL;DR: Theoretical models that have been proposed and applied to proton transfer reactions are reviewed in this paper, where simple models, like the Eigen model, Marcus theory and the intersecting state model, are applied to excited-state intermolecular proton transfers.
read more
Abstract: Theoretical models that have been proposed and applied to proton transfer reactions are reviewed in this work. Simple models, like the Eigen model, Marcus theory and the intersecting state model, are applied to excited-state intermolecular proton transfers. The kinetics and thermodynamics of proton transfers occuring in the singlet states of aromatic molecules with OH, NH3+, NH2 and CO substituents are reviewed.
read more
Chat with Paper
AI Agents for this Paper
Find similar papers on Google Scholar, PubMed and Arxiv
Write a critical review of this paper
Analyze citations of this paper to find unaddressed research gaps
Citations
Proton-Coupled Electron Transfer
David R. Weinberg,Christopher J. Gagliardi,Jonathan F. Hull,Christine Fecenko Murphy,Caleb A. Kent,Brittany C. Westlake,Amit Paul,Daniel H. Ess,Dewey G. McCafferty,Thomas J. Meyer +9 more
TL;DR: Proton-coupled electron transfer is an important mechanism for charge transfer in a wide variety of systems including biology- and materials-oriented venues and several are reviewed.
Advanced Organic Optoelectronic Materials: Harnessing Excited-State Intramolecular Proton Transfer (ESIPT) Process
Ji Eon Kwon,Soo Young Park +1 more
TL;DR: Recent studies on advanced ESIPT molecules and their optoelectronic applications are surveyed, particularly focusing on chemical sensors, fluorescence imaging, proton transfer lasers, and organic light-emitting diodes (OLEDs).
1K
Excited-state intramolecular proton-transfer (ESIPT)-inspired solid state emitters
Vikas S. Padalkar,Shu Seki +1 more
TL;DR: This review highlights recently developed solid state ESIPT emitters with focus on molecular design strategies and their photophysical properties, reported in the last five years.
911
Excited-state proton transfer: from constrained systems to "super" photoacids to superfast proton transfer.
TL;DR: This work has used knowledge of the electronic structure of excited states of acids to design molecules that exhibit enhanced excited-state acidity and are the strongest reversible photoacids known.
773
Excited-state proton transfer reactions II. Intramolecular reactions
TL;DR: In this paper, the intrinsic processes and mechanisms of proton transfer in relation to the nature of the intramolecular hydrogen bond ring are reviewed. But the authors focus on the intrinsic process and not the mechanisms of transfer.
698
References
Kinetics of Fluorescence Quenching by Electron and H‐Atom Transfer
Dieter Rehm,Albert Weller +1 more
TL;DR: In this article, the rate constants of 60 typical electron donor-acceptor systems have been measured in de-oxygenated acetonitrile and are shown to be correlated with the free enthalpy change, ΔG23, involved in the actual electron transfer process.
3.7K
Proton Transfer, Acid‐Base Catalysis, and Enzymatic Hydrolysis. Part I: ELEMENTARY PROCESSES
TL;DR: In this paper, the authors present a relatively complete picture of the elementary proton transfer mechanisms and a comprehensive description of the modes and laws of acid-base and enzymatic catalysis.
1.7K
Theoretical relations among rate constants, barriers, and Broensted slopes of chemical reactions
TL;DR: In this paper, a simple relation, ΔF* = (λ(1 + Δ/λ)^2)/4, was explored in a slightly modified version for reactions with considerable resonance splitting, such as atom transfers, proton transfers, and strong-overlap electron transfers.
1K
Excited-state proton transfer reactions II. Intramolecular reactions
TL;DR: In this paper, the intrinsic processes and mechanisms of proton transfer in relation to the nature of the intramolecular hydrogen bond ring are reviewed. But the authors focus on the intrinsic process and not the mechanisms of transfer.
698