Elucidation of flexible metal-organic frameworks: Research progresses and recent developments

TL;DR: An overview of the historic evolution of porosity and activation of MOFs is provided, followed by a synopsis of the strategies to design and preserve permanent porosity in MOFs.

TL;DR: A taxonomy of guest-induced structural phase transitions and the corresponding isotherms is proposed and generic conditions for observing a double structural transition upon adsorption are derived, often resulting in a two-step isotherm.

TL;DR: The fundamental chemistry of SPCs is discussed by characterizing their common structural features and the resulting structural softness and transitions and focuses on the recently emerging properties based on metastable transitions and those arising from local dynamics.

TL;DR: This work synthesized an organic cage molecule (Cage-6-NH2) that was used as a triangular prism node to yield the first cage-based 3D COF, 3D-CageCOF-1, which adopts an unreported 2-fold interpenetrated acs topology and exhibits reversible dynamic behavior.

TL;DR: Comparing the results to the fastest reported vectorized Cray Y-MP and C90 algorithm shows that the current generation of parallel machines is competitive with conventional vector supercomputers even for small problems.

TL;DR: A new implementation of the molecular simulation toolkit GROMACS is presented which now both achieves extremely high performance on single processors from algorithmic optimizations and hand-coded routines and simultaneously scales very well on parallel machines.

TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.

TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.