Journal Article10.1126/SCIENCE.1158736
Electrochemical Capacitors for Energy Management
John R. Miller,Patrice Simon +1 more
TL;DR: Electrochemical capacitors enable rapid storage and efficient delivery of electrical energy in heavy-duty applications and are being enabled by electrochemical capacitor technology.
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Abstract: Rapid storage and efficient delivery of electrical energy in heavy-duty applications are being enabled by electrochemical capacitors.
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Citations
General solution growth of mesoporous NiCo2O4 nanosheets on various conductive substrates as high-performance electrodes for supercapacitors.
TL;DR: As a highly integrated binder- and conductive-agent-free electrode for supercapacitors, the mesoporous NiCo(2) O(4) nanosheets supported on Ni foam deliver ultrahigh capacitance and excellent high-rate cycling stability.
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Flexible Solid-State Supercapacitors Based on Carbon Nanoparticles/MnO2 Nanorods Hybrid Structure
Longyan Yuan,Xihong Lu,Xihong Lu,Xu Xiao,Teng Zhai,Teng Zhai,Junjie Dai,Fengchao Zhang,Bin Hu,Xue Wang,Xue Wang,Li Gong,Jian Chen,Chenguo Hu,Yexiang Tong,Jun Zhou,Zhong Lin Wang,Zhong Lin Wang +17 more
TL;DR: A highly flexible solid-state supercapacitor was fabricated through a simple flame synthesis method and electrochemical deposition process based on a carbon nanoparticles/MnO(2) nanorods hybrid structure using polyvinyl alcohol/H(3)PO(4) electrolyte to highlight the path for its enormous potential in energy management.
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High-power lithium batteries from functionalized carbon-nanotube electrodes
Seung Woo Lee,Naoaki Yabuuchi,Betar M. Gallant,Shuo Chen,Byeong Su Kim,Paula T. Hammond,Yang Shao-Horn +6 more
TL;DR: In this article, layer-by-layer techniques are used to assemble an electrode that consists of additive-free, densely packed and functionalized multi-walled carbon nanotubes, which can store lithium up to a reversible gravimetric capacity of approximately 200 mA h g(-1) while also delivering 100 kW kg(electrode) of power and providing lifetimes in excess of thousands of cycles.
Understanding electrochemical potentials of cathode materials in rechargeable batteries
TL;DR: In this article, the material characteristics that determine and influence the electrochemical potentials of electrodes are discussed, in particular the cathode materials that convert electricity and chemical potential through electrochemical intercalation reactions.
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High-Power Lithium Batteries from Functionalized Carbon Nanotube Electrodes
Seung Woo Lee,Naoaki Yabuuchi,Betar M. Gallant,Paula T. Hammond,Yang Shao-Horn +4 more
- 08 Jul 2010
TL;DR: Layer-by-layer techniques are used to assemble an electrode that consists of additive-free, densely packed and functionalized multiwalled carbon nanotubes, which had a gravimetric energy approximately 5 times higher than conventional electrochemical capacitors and power delivery approximately 10 timesHigher than conventional lithium-ion batteries.
995
References
Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer
TL;DR: The results challenge the long-held axiom that pores smaller than the size of solvated electrolyte ions are incapable of contributing to charge storage.
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Conducting polymers as electrode materials in supercapacitors
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Use of KCl Aqueous Electrolyte for 2 V Manganese Oxide/Activated Carbon Hybrid Capacitor
TL;DR: In this paper, a hybrid capacitor in neutral KCl aqueous electrolyte, which consists of amorphous manganese oxide (a-MnO 2.nH 2 O) as a cathode and activated carbon as an anode, was reported.
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Cycling stability of a hybrid activated carbon//poly(3-methylthiophene) supercapacitor with N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ionic liquid as electrolyte
Andrea Balducci,Wesley A. Henderson,Marina Mastragostino,Stefano Passerini,Patrice Simon,Francesca Soavi +5 more
TL;DR: In this article, a solvent-free green electrolyte for high-voltage hybrid supercapacitors was developed, and the cyclability of a laboratory scale cell with electrode mass loading sized for practical uses was tested at 60°C over 16,000 galvanostatic charge-discharge cycles at 10 µm −2 in the 1.5 and 3.6 µm voltage range.
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Mathematical Model of Heterogeneous Electrochemical Capacitors and Calculation of Their Parameters
TL;DR: In this article, a mathematical model of heterogeneous electrochemical supercapacitors (HES) is proposed which makes it possible to develop capacitors with optimal designs and make calculations of their energy, capacity, and power parameters.
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