Journal Article10.1002/CPLU.202000584
Electrochemical Applications of Ferrocene-Based Coordination Polymers.
Mao-Lin Hu,Mahsa Abbasi-Azad,Behnam Habibi,Farzaneh Rouhani,Hamed Moghanni-Bavil-Olyaei,Kuan-Guan Liu,Ali Morsali +6 more
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TL;DR: The synthesis and electrochemical applications of Fc-CPs are described and how the incorporation of ferrocene units into coordination polymers containing other metals results in unprecedented properties are revealed.
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Abstract: Ferrocene and its derivatives, especially ferrocene-based coordination polymers (Fc-CPs), offer the benefits of high thermal stability, two stable redox states, fast electron transfer, and excellent charge/discharge efficiency, thus holding great promise for electrochemical applications. Herein, we describe the synthesis and electrochemical applications of Fc-CPs and reveal how the incorporation of ferrocene units into coordination polymers containing other metals results in unprecedented properties. Moreover, we discuss the usage of Fc-CPs in supercapacitors, batteries, and sensors as well as further applications of these polymers, for example in electrocatalysts, water purification systems, adsorption/storage systems.
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TL;DR: The use of ferrocene in bio-organometallic chemistry has been growing rapidly, and several promising applications have been developed since ferrocenes is a stable, nontoxic compound and has good redox properties as mentioned in this paper.
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TL;DR: A critical review of the emerging field of MOFs for photon collection and subsequent energy transfer is presented, including examples involving MOF-quantum dots and molecular chromophores.
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Towards a Further Generation of High‐Energy Carbon‐Based Capacitors by Using Redox‐Active Electrolytes
TL;DR: This work was supported by MICINN (Project MAT2007-61467), and S.R. thanks MICinN for an FPI doctoral grant.