Journal Article10.1016/S0277-5387(01)00744-6
Electrochemical and spectroscopic studies on RuCl2(PPh3)2(N)2 and RuCl2(PPh3)2(N-N) complexes (N = pyridine derivatives and N-N = phenanthroline or bipyridine derivatives. X-ray structure of RuCL2(PPh3)2(phen)
Alzir A. Batista,Marcelo O. Santiago,Claudio Luis Donnici,Ícaro de Sousa Moreira,Peter Conrad Healy,Susan J. Berners-Price,Salete L Queiroz +6 more
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TL;DR: A series of RuCl2(PPh3)2(N)2 and RuCl 2(Pph3)3(N)-N 2 complexes were synthesized from a single crystal X-ray crystallography as discussed by the authors, which were characterized by elemental analysis, cyclic voltammetry and UV-Vis.
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About: This article is published in Polyhedron. The article was published on 15 Jul 2001. The article focuses on the topics: Bipyridine & Isonicotinamide.
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Citations
Ru(II)-based complexes with N-(acyl)-N',N'-(disubstituted)thiourea ligands: Synthesis, characterization, BSA- and DNA-binding studies of new cytotoxic agents against lung and prostate tumour cells.
Rodrigo S. Corrêa,Kátia de Oliveira,Fábio G. Delolo,Anislay Alvarez,Raúl Mocelo,Ana M. Plutín,Márcia Regina Cominetti,Eduardo E. Castellano,Alzir A. Batista +8 more
TL;DR: Four ruthenium(II)-based complexes with N-(acyl)-N',N'-(disubstituted)thiourea derivatives (Th) were obtained and it was revealed that the complexes are more active in tumour cells than in normal cells, and that they present high cytotoxicity compared with the reference metallodrug, cisplatin.
74
Antiparasitic activities of novel ruthenium/lapachol complexes
Marília I.F. Barbosa,Rodrigo S. Corrêa,Kátia de Oliveira,Claudia Rodrigues,Javier Ellena,Otaciro R. Nascimento,Vinícius Pinto Costa Rocha,Fabiana Regina Nonato,Taís S. Macedo,José Maria Barbosa-Filho,Milena Botelho Pereira Soares,Milena Botelho Pereira Soares,Alzir A. Batista +12 more
TL;DR: The evaluation of the antiparasitic activities of the complexes against Leishmania amazonensis and Plasmodium falciparum demonstrated that Lapachol-ruthenium complexes are more potent than the free lapachol.
69
Bifunctional RuII -Complex-Catalysed Tandem C-C Bond Formation: Efficient and Atom Economical Strategy for the Utilisation of Alcohols as Alkylating Agents.
TL;DR: Catalytic activities of a series of functional bipyridine-based RuII complexes in β-alkylation of secondary alcohols using primary alcohols were investigated and complex 3 a demonstrated the highest reactivity compared to all the reported transition metal complexes in this reaction.
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Ruthenium Phosphine/Diimine Complexes: Syntheses, Characterization, Reactivity with Carbon Monoxide, and Catalytic Hydrogenation of Ketones
Márcio P. de Araujo,Alberthmeiry T. de Figueiredo,André L. Bogado,Gustavo Von Poelhsitz,Javier Ellena,Eduardo E. Castellano,Claudio Luis Donnici,Joao V. Comasseto,Alzir A. Batista +8 more
TL;DR: In this paper, the authors used a single reduction process (RuIII/RuII) and showed that these complexes are more easily oxidized than their analogues cis-[RuCl2(dppb)(N−N)].
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Ruthenium(II) complexes of 1,3-thiazolidine-2-thione: Cytotoxicity against tumor cells and anti-Trypanosoma cruzi activity enhanced upon combination with benznidazole.
Rodrigo S. Corrêa,Monize M. da Silva,Angelica E. Graminha,Cássio Santana Meira,Jamyle Andrade Ferreira dos Santos,Diogo Rodrigo Magalhães Moreira,Milena Botelho Pereira Soares,Gustavo Von Poelhsitz,Eduardo E. Castellano,Carlos Bloch,Márcia Regina Cominetti,Alzir A. Batista +11 more
TL;DR: It is demonstrated that Ru(II) complexes have powerful pharmacological activity, while the metal-free tzdtH does not provoke the same outcome.
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References
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Infrared and Raman Spectra of Inorganic and Coordination Compounds
Kazuo Nakamoto
- 01 Jan 1978
TL;DR: In this article, the normal modes of vibration are illustrated and corresponding vibrational frequencies are listed for each type, including diatomic, triatomic, fouratomic, five-atomic, six-atomic and seven-atomic types.
•Book
Infrared and Raman spectra of inorganic and coordination compounds
Kazuo Nakamoto
- 01 Jan 1997
TL;DR: In this article, the normal modes of vibration are illustrated and corresponding vibrational frequencies are listed for each type, including diatomic, triatomic, fouratomic, five-atomic, six-atomic and seven-atomic types.
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