Journal Article10.1016/0010-8545(87)80007-3
η5-Heterocyclic metal carbonyls
David L. Kershner,Fred Basolo +1 more
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About: This article is published in Coordination Chemistry Reviews. The article was published on 01 Jul 1987. The article focuses on the topics: Reactivity (chemistry) & Bicyclic molecule.
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Citations
Recent advances in high oxidation state Mo and W imido alkylidene chemistry.
TL;DR: In 1956 Eleuterio invoked what is now known as an olefin metathesis reaction in order to explain how certain heterogeneous Mo catalysts could produce polyethylene from propylene; he proposed that propylene was converted into 2-butene and ethylene and that ethylene was then selectively polymerized.
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An overview of modeling studies in HDS, HDN and HDO catalysis
TL;DR: In this paper, the authors highlight organometallic and clean surface model studies that offer realistic ways of understanding details of hydrodesulfurization, hydrodenitrogenation, and hydrodeoxygenation reactions as they occur on heterogeneous hydrotreating catalysts.
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Dipyrrolyl precursors to bisalkoxide molybdenum olefin metathesis catalysts.
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References
Basicity of metal carbonyl complexes: XIX. Co substitution in azacymantrene and reactions of (η5-C4H4N)Mn(CO)2PPh3 with electrophiles. X-ray crystal structure of [(PPh3)(CO)2Mn(η5-C4H4N)]2PdCl2☆
TL;DR: In this paper, a method for substituting a CO ligand in azacymantrene, (η 5 - C 4 H 4 N)Mn(CO) 3 (I), by the interaction of I with PPh 3 in the presence of Me 3 NO has been found.
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Basicity of metal carbonyl complexes
TL;DR: The cyclopentadienylmanganesetricarbonyl and cyclopendienyldic-branching derivatives of manganese and rhenium react with aluminum bromide in benzene to give predominantly adducts at the CO (or NO) oxygen as mentioned in this paper.
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