Journal Article10.1021/NL047955Q
Dumbbell-like Bifunctional Au−Fe3O4 Nanoparticles
1.2K
TL;DR: The dumbbell is formed through epitaxial growth of iron oxide on the Au seeds, and the growth can be affected by the polarity of the solvent, as the use of diphenyl ether results in flower-like Au-Fe(3)O(4) nanoparticles.
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Abstract: Dumbbell-like Au−Fe3O4 nanoparticles are synthesized using decomposition of Fe(CO)5 on the surface of the Au nanoparticles followed by oxidation in 1-octadecene solvent. The size of the particles is tuned from 2 to 8 nm for Au and 4 nm to 20 nm for Fe3O4. The particles show the characteristic surface plasmon absorption of Au and the magnetic properties of Fe3O4 that are affected by the interactions between Au and Fe3O4. The dumbbell is formed through epitaxial growth of iron oxide on the Au seeds, and the growth can be affected by the polarity of the solvent, as the use of diphenyl ether results in flower-like Au−Fe3O4 nanoparticles.
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Citations
Size distribution and interaction effects on dispersed Fe30Ni70 nanoalloy synthesized by thermal decomposition
TL;DR: In this paper, a simple modification of the random anisotropy model (RAM) was used to describe noninteracting particles system and the size distribution of nanoparticles should also play a crucial role in determining the magnetic behavior of the sample.
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Synthesis and Characterization of Magnetic–Plasmonic Hybrid Nanoparticles
Mari Takahashi,Ryoichi Kitaura,Priyank Mohan,Shinya Maenosono +3 more
- 01 Jan 2019
TL;DR: Synthetic protocols, structures, and physical properties of different types of magnetic–plasmonic hybrid nanoparticles are outlined and several examples of hyperthermia using magnetic and/or plAsmonic particles are described.
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The key role of nanoparticle seeds during site-selective growth of silver to fabricate core-shell or asymmetric dumbbell heterostructures.
TL;DR: A novel method to induce site-specific deposition of plasmonic silver domain on controlled sites of seeded AgBr nanoparticles is designed and the significant role of seed size during seeded silver growth has been demonstrated.
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A Facile Route Towards Inorganic Particles with Two Distinct Compartments Based on Electro‐Hydrodynamic Co‐Jetting
Abstract: The design and synthesis of Janus particles has been of broad interest in recent years because of their importance for both of fundamental and applied sciences. [ 1 ] Initially, the main emphasis has been placed on controlling the surface patchiness of particles, where the anisotropy originates from asymmetrical surface functionalities. [ 2 ] More recently, multicompartmental particles have emerged that feature compositionally distinct pockets of distinct materials. [ 3 ] The multicompartmental architecture not only gives rise to defi ned surface patterns, but can result in distinct bulk compartments and therefore truly anisotropic functionalities. Although a number of methods to control surface patchiness, such as line-of-side deposition of metals, or selective surface modifi cation, are similarly applicable to organic as well as inorganic particles, very little is known about bulk-compartmentalized inorganic microand nanoparticles. [ 2b, 4 ] Preparation of purely inorganic particles with defi ned compartmentalization has been more challenging, and their preparation has been limited to toposelective surface modifi cation, [ 5 ] template-directed self-assembly, [ 6 ] controlled phase separation, [ 7 ] and controlled surface nucleation. [ 8 ] Impressive particles including dumbbell-, snowmanor acorn-like particles have been prepared based on these methods to date. Herein, we report a novel approach towards compartmentalized inorganic microparticles using EHD co-jetting with mixtures of inorganic precursors and organic polymers followed
Transforming micron-sized cross-link PS microspheres from isotropy to anisotropy with the assistance of supercritical carbon dioxide and sonication
TL;DR: In this paper, a two-stage dispersion polymerization method was used to synthesize polystyrene (PS) microspheres with hard shell and soft core, which were welded together and the submicron-sized pits were engraved on the surfaces of these particles.
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