Journal Article10.1021/CR100198W
Direct C-H transformation via iron catalysis.
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About: This article is published in Chemical Reviews. The article was published on 01 Mar 2011.
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Citations
Mild synthesis of chalcones via rhodium(III)-catalyzed C-C coupling of arenes and cyclopropenones
Songjie Yu,Xingwei Li +1 more
TL;DR: A Rh(III)-catalyzed aryl C-H bond insertion into cyclopropenones via a C- H activation pathway has been reported, providing chalcones in excellent yields under mild conditions.
95
Iron-Catalyzed N-Alkylation of Azoles via Cleavage of an sp3 C–H Bond Adjacent to a Nitrogen Atom
TL;DR: Iron-catalyzed direct C-N bond formation between azoles and amides is described and oxidative coupling reactions of sp(3) C-H bonds adjacent to a nitrogen atom in amides and sulfonamides with the N-H bond in azoles proceeded smoothly in the presence of FeCl(2) and di-tert-butyl peroxide (DTBP).
93
Iron‐Catalyzed Oxidative Amidation of Tertiary Amines with Aldehydes
TL;DR: A new oxidative coupling protocol for amide bond formation has been developed andMechanistic studies indicated that a peroxide and an iminium ion act as the reactive intermediates in this oxidative amidation.
93
Re/Mg Bimetallic Tandem Catalysis for [4+2] Annulation of Benzamides and Alkynes via C-H/N-H Functionalization
TL;DR: A wide range of both cis- and trans-3,4-dihydroisoquinolinones is expediently synthesized in a highly atom-economical manner, and mechanistic studies unraveled a tandem mode of action between rhenium and magnesium in the catalytic cycles.
93
Direct silylation reactions of inert C-H bonds via transition metal catalysis
Yunhui Yang,Congyang Wang +1 more
TL;DR: In this article, the silylation reactions of inert C-H bonds catalyzed by transition metal complexes of Ir, Rh, Ru, Pt, Pd, Ni, and Sc have been summarized.
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References
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Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
TL;DR: This is the first comprehensive review encompassing the large body of work in this field over the past 5 years, and will focus specifically on ligand-directed C–H functionalization reactions catalyzed by palladium.
Metal-catalyzed cross-coupling reactions
Armin de Meijere,François Diederich +1 more
- 25 Aug 2004
TL;DR: In this paper, the authors present an approach to the formation of C-X (X = N, O, S) bonds in metal-catalyzed cross-coupling reactions.
Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality.
TL;DR: A review of palladium-catalyzed coupling of CH bonds with organometallic reagents through a PdII/Pd0 catalytic cycle can be found in this paper.
The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
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