Direct C-H transformation via iron catalysis.

TL;DR: Late-stage functionalization of the incorporated silyl moieties facilitates the synthesis of N-formyl, cis-enamine, β-hydroxyl, amino, and pyrrole-containing derivatives.

TL;DR: The work reported here illustrates that Fe(CO)5 can also act as a ligand and shows that it is possible to manipulate the coordination sphere at silver while keeping the Ag-Fe bond intact.

TL;DR: In this paper, a new CuI/DMSO-mediated oxidative domino process was developed for the synthesis of tryptanthrin derivatives from 2-aminoaryl methyl ketones and isatoic anhydrides through copper-promoted oxidative functionalization.

TL;DR: An effective indium-catalyzed oxidative cross-dehydrogenative coupling of electronically varied chromenes with 1,3-dicarbonyl compounds and aryl rings has been established and both the C-H alkylation and aRYlation proceed smoothly at room temperature to afford diverse α-substituted chromene compounds in up to 91% yields.

TL;DR: This is the first comprehensive review encompassing the large body of work in this field over the past 5 years, and will focus specifically on ligand-directed C–H functionalization reactions catalyzed by palladium.

TL;DR: In this paper, the authors present an approach to the formation of C-X (X = N, O, S) bonds in metal-catalyzed cross-coupling reactions.

TL;DR: A review of palladium-catalyzed coupling of CH bonds with organometallic reagents through a PdII/Pd0 catalytic cycle can be found in this paper.

TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.