Journal Article10.1021/CR100198W
Direct C-H transformation via iron catalysis.
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About: This article is published in Chemical Reviews. The article was published on 01 Mar 2011.
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Citations
Cross Dehydrogenative Coupling (CDC) Reactions of N,N-Disubstituted Formamides, Benzaldehydes and Cycloalkanes
TL;DR: In this article, a review article highlights recent advances in cross dehydrogenative coupling reactions for C-C and C-heteroatom bond formation with the above substrates, showing that in the absence of a benzylic C-H site or a heteroatom at the α-position, these substrates react efficiently under oxidative conditions.
48
Gold Nanoparticle–Polydopamine–Reduced Graphene Oxide Ternary Nanocomposite as an Efficient Catalyst for Selective Oxidation of Benzylic C(sp3)−H Bonds Under Mild Conditions
TL;DR: A ternary nanocomposite comprising of Au nanoparticles (NPs), polydopamine, and reduced graphene oxide exhibits excellent activity and selectivity towards the oxidation of C−H bonds in benzylic hydrocarbons under mild conditions in the presence of N−hydroxyphthalimide as discussed by the authors.
48
Arylation/Intramolecular Conjugate Addition of 1,6-Enynes Enabled by Manganese(I)-Catalyzed C–H Bond Activation
Yun-Xuan Tan,Xing-Yu Liu,Xing-Yu Liu,Yi-Shuang Zhao,Ping Tian,Ping Tian,Guo-Qiang Lin,Guo-Qiang Lin,Guo-Qiang Lin +8 more
TL;DR: An arylation/intramolecular conjugate addition of cyclohexadienone-containing 1,6-enynes has been established through initiation by manganese(I)-catalyzed C-H bond activation and involved unusual E/ Z-isomerized alkenyl-Mn intermediates.
48
Synergistic H4NI–AcOH Catalyzed Oxidation of the Csp3–H Bonds of Benzylpyridines with Molecular Oxygen
TL;DR: The oxidation of benzylpyridine forming benzoylpyridines was achieved based on a synergistic H4NI-AcOH catalyst and molecular oxygen in high yield under solvent-free conditions using molecular oxygen as the oxidant and has a wide scope of substrates and excellent chemoselectivity.
48
Iron-Catalyzed Hydrogen Transfer Reduction of Nitroarenes with Alcohols: Synthesis of Imines and Aza Heterocycles.
Jiajun Wu,Christophe Darcel +1 more
TL;DR: A straightforward and selective reduction of nitroarenes with various alcohols was efficiently developed using an iron catalyst via a hydrogen transfer methodology, which led specifically to imines in 30-91% yields, with a good functional group tolerance.
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References
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F. Albert Cotton
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Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
TL;DR: This is the first comprehensive review encompassing the large body of work in this field over the past 5 years, and will focus specifically on ligand-directed C–H functionalization reactions catalyzed by palladium.
Metal-catalyzed cross-coupling reactions
Armin de Meijere,François Diederich +1 more
- 25 Aug 2004
TL;DR: In this paper, the authors present an approach to the formation of C-X (X = N, O, S) bonds in metal-catalyzed cross-coupling reactions.
Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality.
TL;DR: A review of palladium-catalyzed coupling of CH bonds with organometallic reagents through a PdII/Pd0 catalytic cycle can be found in this paper.
The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
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