Journal Article10.1039/C6PY01874B
Differences in electroactive terpolymers based on VDF, TrFE and 2,3,3,3-tetrafluoropropene prepared by batch solution and semi-continuous aqueous suspension polymerizations
Thibaut Soulestin,Thibaut Soulestin,Vincent Ladmiral,Thierry Lannuzel,Fabrice Domingues Dos Santos,Bruno Ameduri +5 more
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TL;DR: In this article, a semi-continuous aqueous suspension polymerization process was used for the synthesis of terpolymers with a more homogeneous composition, and the thermal and ferroelectric properties of the homogeneous and heterogeneous ter polymers were characterized and compared.
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About: This article is published in Polymer Chemistry. The article was published on 24 Jan 2017. The article focuses on the topics: Polymerization & Solution polymerization.
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Citations
Vinylidene fluoride- and trifluoroethylene-containing fluorinated electroactive copolymers. How does chemistry impact properties?
Thibaut Soulestin,Thibaut Soulestin,Vincent Ladmiral,Fabrice Domingues Dos Santos,Bruno Ameduri +4 more
TL;DR: A detailed overview of semi-crystalline poly(VDF- co -TrFE) copolymers and their ferroelectric properties from the point of view of polymer chemists is provided in this paper.
198
•Journal Article
Novel Polymer Ferroelectric Behavior via Crystal Isomorphism and Nanoconfinement Effect
TL;DR: In this article, the basic physics of poly(vinylidene fluoride- co-trifluoroethylene) [P(VDF-TrFE)]-based terpolymers, electron-beam (e-beam) irradiated P (VDF)-TrFE) copolymers, and PVDF graft copolymer were investigated.
176
Design, synthesis and processing of PVDF-based dielectric polymers
Shan Wang,Qi Li +1 more
- 05 Jun 2018
TL;DR: In this paper, the authors introduce the current practical/promising applications of polyvinylidene fluoride (PVDF)-based dielectric polymers, and the corresponding optimum dielectrics polarisation behavior and crystal structure are proposed accordingly.
61
Copolymers of Vinylidene fluoride with Functional comonomers and Applications therefrom: Recent Developments, Challenges and Future Trends
TL;DR: In this paper , the radical copolymerization of VDF with M monomer is discussed and the properties and applications of the resulting copolymers are presented, after listing a non-exhaustive series of comonomers and macromonomers, and their reactivity towards VDF deduced from the kinetics of copolymization to suggest a reactivity order.
Understanding the Paraelectric Double Hysteresis Loop Behavior in Mesomorphic Even-Numbered Nylons at High Temperatures
TL;DR: In this paper, temperature-dependent ferroelectric behavior was studied for mesomorphic even-numbered nylons (i.e., nylon-12 and nylon-6) using electric displacement-electric field (D-E) loop measurements.
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References
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Principles of polymerization
George G. Odian
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TL;DR: In this paper, the authors present an overview of the properties of polymers and their applications in the literature, including the following: 1.1 Types of Polymers and Polymerization. 2.3 Linear, Branched, and Crosslinked Polymers.
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Living free-radical polymerization by reversible addition - Fragmentation chain transfer: The RAFT process
John Chiefari,Y. K. Chong,Frances Ercole,Julia Krstina,Justine Leigh Jeffery,Tam P. T. Le,Roshan T. A. Mayadunne,Gordon Francis Meijs,Catherine Louise Moad,Graeme Moad,Ezio Rizzardo,San H. Thang +11 more
TL;DR: The authors proposed a reversible additive-fragmentation chain transfer (RAFT) method for living free-radical polymerization, which can be used with a wide range of monomers and reaction conditions and in each case it provides controlled molecular weight polymers with very narrow polydispersities.
Controlled/living radical polymerization: Features, developments, and perspectives
TL;DR: In this article, a review of recent mechanistic developments in the field of controlled/living radical polymerization (CRP) is presented, with particular emphasis on structure-reactivity correlations and "rules" for catalyst selection in ATRP, for chain transfer agent selection in reversible addition-fragmentation chain transfer (RAFT) polymerization, and for the selection of an appropriate mediating agent in stable free radical polymerisation (SFRP), including organic and transition metal persistent radicals.
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Living radical polymerization by the RAFT process
TL;DR: A review of living radical polymerization achieved with thiocarbonylthio compounds by a mechanism of reversible addition-fragmentation chain transfer (RAFT) is presented in this article.