Journal Article10.1016/J.CCR.2005.05.008
Design and synthesis of structurally well-defined functional polyolefins via transition metal-mediated olefin polymerization chemistry
Jin-Yong Dong,Youliang Hu +1 more
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TL;DR: In this paper, a review of recent achievements in the functionalization of polyolefins is presented, with special attention being paid to the chemistries using transition metal-catalyzed process to synthesize structurally well-defined functional polyolefs, including side group-functionalized polyolefin, chain end-functionalised polyolein and functional polyine with graft and block structures.
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About: This article is published in Coordination Chemistry Reviews. The article was published on 01 Jan 2006.
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Citations
Polymethylene-b-poly(styrene-co-2,3,4,5,6-pentafluoro styrene) copolymers: synthesis and fabrication of their porous films
Yang Xue,Yang Xue,Hui-Chao Lu,Hui-Chao Lu,Qiao-Ling Zhao,Jin Huang,Shengang Xu,Shaokui Cao,Zhi Ma +8 more
TL;DR: In this paper, a block copolymer of polymethylene-b-poly(styrene-co-2,3,4,5,6-pentafluoro styrene) (PM-B-P(St-Co-PFSt)) with controlled molecular weight and narrow molecular weight distribution was synthesized via a combination of polyhomologation of ylides and ATRP copolymers of styrene.
Synthesis and self-assembly of isotactic polystyrene-block-poly(ethylene glycol)
TL;DR: The behavior and micelle morphology of the crystallization-driven self-assembly of isotactic polystyrene block-poly(ethylene glycol) in N,N-dimethylformamide (DMF) were investigated by scanning electron microscopy and X-ray diffraction as discussed by the authors.
Synthesis of functional polyolefins using cationic bisphosphine monoxide-palladium complexes.
Brad P. Carrow,Kyoko Nozaki +1 more
TL;DR: Cationic palladium complexes can exhibit good activity for polymerizations of polar monomers, in contrast to cationic α-diimine palladiumcomplex (Brookhart-type) that are not applicable to industrially relevant polar monomer beyond acrylates.
Material Properties of Functional Polyethylenes from Transition-Metal-Catalyzed Ethylene–Polar Monomer Copolymerization
Chen Tan,Chen Zou,Changle Chen +2 more
TL;DR: In this paper , the authors summarized some recent advances in the improvements in surface and compatibilities properties induced through polar group incorporation as well as some custom-made properties such as elastic, flame-retardant, antibacterial, antioxidant, cross-linking, self-healing, light response, dynamic cross-link, and photodegradation properties.
Reactivity Comparison of ω-Alkenols and Higher 1-Alkenes in Copolymerization with Propylene Using An Isospecific Zirconocene-MMAO Catalyst
TL;DR: In this article, aluminum-protected copolymerization of propylene with ω-alkenols was conducted with a rac-[Me2Si(2-Me-4-Ph-Ind)2]ZrCl2 activated by modified methylaluminoxane.
References
Neutral, single-component nickel (II) polyolefin catalysts that tolerate heteroatoms
Todd Ross Younkin,Eric Connor,Jason I. Henderson,Stefan K. Friedrich,Robert H. Grubbs,Donald A. Bansleben +5 more
TL;DR: A family of catalysts has been developed whose members are tolerant of both heteroatoms and less pure starting materials, and which produce high-molecular-weight polyethylene, polymerize functionalized olefins, and require no cocatalyst.
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Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate
TL;DR: In this article, the effects of reaction conditions and catalyst structure on the copolymerization reaction were rationalized, and the effect of the acrylate comonomer at the ends of branches as −CH2CH2C(O)OMe groups was analyzed.
Copolymerization of polar monomers with olefins using transition-metal complexes.
Lisa S. Boffa,Bruce M. Novak +1 more
TL;DR: One of the most challenging targets is the controlled copolymerization of simple olefins with polar functional monomers, which would mark a quantum advance in polyolefin field.
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