Journal Article10.1016/J.CCR.2005.05.008
Design and synthesis of structurally well-defined functional polyolefins via transition metal-mediated olefin polymerization chemistry
Jin-Yong Dong,Youliang Hu +1 more
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TL;DR: In this paper, a review of recent achievements in the functionalization of polyolefins is presented, with special attention being paid to the chemistries using transition metal-catalyzed process to synthesize structurally well-defined functional polyolefs, including side group-functionalized polyolefin, chain end-functionalised polyolein and functional polyine with graft and block structures.
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About: This article is published in Coordination Chemistry Reviews. The article was published on 01 Jan 2006.
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Citations
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Synthesis of Brominated Polyethylene by Copolymerization of Ethylene with ω–bromoalkene Catalyzed by a Metallocene and Methylaluminoxane System
TL;DR: In this article, a modified methylaluminoxane (MMAO) solution was used as a cocatalyst and rac-Et(H4Ind)2ZrCl2 as a catalyst.
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Preparation of functionalized poly(1-butene) from 1,2-polybutadiene via sequential thiol-ene click reaction and ring-opening polymerization
TL;DR: In this paper, a quasi-poly(1-butene) polymer containing CC double bonds was modified by subjecting the polymer to a thiol-ene reaction in the presence of thiol compounds.
References
Neutral, single-component nickel (II) polyolefin catalysts that tolerate heteroatoms
Todd Ross Younkin,Eric Connor,Jason I. Henderson,Stefan K. Friedrich,Robert H. Grubbs,Donald A. Bansleben +5 more
TL;DR: A family of catalysts has been developed whose members are tolerant of both heteroatoms and less pure starting materials, and which produce high-molecular-weight polyethylene, polymerize functionalized olefins, and require no cocatalyst.
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Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate
TL;DR: In this article, the effects of reaction conditions and catalyst structure on the copolymerization reaction were rationalized, and the effect of the acrylate comonomer at the ends of branches as −CH2CH2C(O)OMe groups was analyzed.
Copolymerization of polar monomers with olefins using transition-metal complexes.
Lisa S. Boffa,Bruce M. Novak +1 more
TL;DR: One of the most challenging targets is the controlled copolymerization of simple olefins with polar functional monomers, which would mark a quantum advance in polyolefin field.
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