Journal Article10.1016/0013-4686(67)80098-7
Cyclic voltammetry with asymmetrical potential scan: A simple approach to mechanisms involving moderately fast chemical reactions
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TL;DR: In this paper, the use of trapezoidal and triangular potential-scan methods to the mechanistic analysis of chemical reactions coupled with electron transfer is investigated. But the method is particularly suited to the study of mechanisms involving chemical reactions following the charge transfer or interposed between two consecutive charge transfers, and it is shown that very asymmetric potential scan leads to very simple analysis criteria for characterizing qualitatively and quantitatively the rate determining chemical step.
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About: This article is published in Electrochimica Acta. The article was published on 01 Aug 1967. The article focuses on the topics: Chemical reaction.
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Citations
Cyclic Voltammetry—“Electrochemical Spectroscopy”. New Analytical Methods (25)
TL;DR: The cyclic voltammetry has the further attraction of providing information not only on the thermodynamics of redox processes but also on the kinetics of heterogeneous electron-transfer reactions and coupled chemical reactions as discussed by the authors.
574
Determination of standard rate constants for electrochemical irreversible processes from linear sweep voltammograms
TL;DR: In this paper, a new equation has been deduced from which a direct determination of the standard rate constant from linear sweep voltammograms can be made, and some questions related with the detection limit of irreversibility by means of the linear voltammetric method are also discussed.
212
Potential-sweep voltammetry: Theoretical analysis of monomerization and dimerization mechanisms
TL;DR: In this article, current/potential curves have been calculated for electrode processes involving dimerization of the charge transfer product or formation of the depolarizer by dissociation of an electro-inactive species (monomerization).
111
Electron-Transfer Chain Catalysis in Organotransition Metal Chemistry†
TL;DR: The theoretical and experimental foundations established by Feldberg in 1971 (ECE mechanism) have been applied, using fast electrochemical techniques, to various organometallic reactions such as isomerization, ligand exchange, chelation, decomplexation, and CO insertion and extrusion.
106
References
Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.
R. S. Nicholson,Irving. Shain +1 more
TL;DR: In this paper, the integral equations obtained from the boundary value problems were solved and extensive data were calculated which permit construction of stationary electrode polarograms from theory, making it possible to develop diagnostic criteria so that unknown systems can be characterized by studying the variation of peak current, half-peak potential, or ratio of anodic to cathodic peak currents as a function of rate of voltage scan.
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