Creep and shrinkage behavior of improved ultrathin polymeric films

TL;DR: In this paper, the authors presented the long-term creep-deformation and shrinkage characteristics of improved ultrathin polymeric films for magnetic tapes, including poly(ethylene terephthalate), poly(methylene naphthalate) (PEN), and aromatic polyamide (ARAMID).

Abstract: Long-term creep-deformation and shrinkage characteristics of improved ultrathin polymeric films for magnetic tapes are presented. These films include poly(ethylene terephthalate) (PET), poly(ethylene naphthalate) (PEN), and aromatic polyamide (ARAMID). PET film is currently the standard substrate used for magnetic tapes, and thinner tensilized-type PET, PEN, and ARAMID have recently been used as alternate substrates with improved material properties. The thickness of the films ranges from 6.2 to 4.8 μm. More dimensional stability is required for advanced magnetic tapes, and the study of creep and shrinkage behavior is important for estimating the dimensional stability. Creep measurements were performed on all available substrates at 25, 40, and 55°C for 100 h. Based on these data, master curves were generated using time–temperature superposition to predict dimensional stability after several years. The amount of creep deformation is considerably smaller for ARAMID and tensilized-type PET than for PEN, although Standard PET shows the largest amount of creep. In addition, creep measurements under high humidity also show similar trends. Shrinkage measurements at 55°C for 100 h show that the shrinkage of ARAMID is lower than that of PET and PEN. The relationship between the polymeric structure and dimensional stability are also discussed. Based on the creep and shrinkage behavior, ARAMID and tensilized-type PET seem to be suitable for advanced magnetic tapes. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1477–1498, 2002; DOI 10.1002/app.10012