Journal Article10.1039/C2CS35072F
Covalent organic frameworks (COFs): from design to applications
San-Yuan Ding,Wei Wang +1 more
3.2K
TL;DR: This critical review describes the state-of-the-art development in the design, synthesis, characterisation, and application of the crystalline porous COF materials.
read more
Abstract: Covalent organic frameworks (COFs) represent an exciting new type of porous organic materials, which are ingeniously constructed with organic building units via strong covalent bonds. The well-defined crystalline porous structures together with tailored functionalities have offered the COF materials superior potential in diverse applications, such as gas storage, adsorption, optoelectricity, and catalysis. Since the seminal work of Yaghi and co-workers in 2005, the rapid development in this research area has attracted intensive interest from researchers with diverse expertise. This critical review describes the state-of-the-art development in the design, synthesis, characterisation, and application of the crystalline porous COF materials. Our own opinions on further development of the COF materials are also presented for discussion (155 references).
read more
Chat with Paper
AI Agents for this Paper
Find similar papers on Google Scholar, PubMed and Arxiv
Write a critical review of this paper
Analyze citations of this paper to find unaddressed research gaps
Citations
Efficient cycloaddition of CO2 to epoxides using novel heterogeneous organocatalysts based on tetramethylguanidine-functionalized porous polyphenylenes
TL;DR: In this paper, a tetramethylguanidine (TMG)-polyphenylene organocatalysts were used for the conversion of CO2 into cyclic carbonates by cycloaddition to epoxides.
55
Covalent-organic frameworks as adsorbent and matrix of SALDI-TOF MS for the enrichment and rapid determination of fluorochemicals.
TL;DR: With the assistance of COF-LZU1, trace levels of fluorochemicals could be quantitatively and sensitively analyzed from environmental water samples in a rapid, sensitive and convenient way.
54
Aptamer-Functionalized Magnetic Conjugated Organic Framework for Selective Extraction of Traces of Hydroxylated Polychlorinated Biphenyls in Human Serum.
TL;DR: A solid-phase extraction adsorbent based on an aptamer-functionalized magnetic conjugated organic framework (COF) was developed for selective extraction of traces of hydroxylated polychlorinated biphenyls and showed good reusability and could be applied in at least ten extraction cycles with recoveries greater than 90 %.
54
An azine-linked covalent organic framework as stationary phase for separation of environmental endocrine disruptors by open-tubular capillary electrochromatography.
TL;DR: A novel azine-linked COF (N0-COF) coated capillary was prepared as OT-CEC separation channel and a new method for separation and detection of environmental endocrine disruptors, i.e., bisphenol A (BPA) and its analogues was established.
54
References
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Hydrogen-storage materials for mobile applications
TL;DR: Recent developments in the search for innovative materials with high hydrogen-storage capacity are presented.
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.
Porous, Crystalline, Covalent Organic Frameworks
Adrien P. Côté,Annabelle I. Benin,Nathan W. Ockwig,Michael O'Keeffe,Adam J. Matzger,Omar M. Yaghi +5 more
TL;DR: Covalent organic frameworks (COFs) have been designed and successfully synthesized by condensation reactions of phenyl diboronic acid and hexahydroxytriphenylene to form rigid porous architectures with pore sizes ranging from 7 to 27 angstroms.
6.4K