Journal Article10.1039/C2CS35072F
Covalent organic frameworks (COFs): from design to applications
San-Yuan Ding,Wei Wang +1 more
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TL;DR: This critical review describes the state-of-the-art development in the design, synthesis, characterisation, and application of the crystalline porous COF materials.
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Abstract: Covalent organic frameworks (COFs) represent an exciting new type of porous organic materials, which are ingeniously constructed with organic building units via strong covalent bonds. The well-defined crystalline porous structures together with tailored functionalities have offered the COF materials superior potential in diverse applications, such as gas storage, adsorption, optoelectricity, and catalysis. Since the seminal work of Yaghi and co-workers in 2005, the rapid development in this research area has attracted intensive interest from researchers with diverse expertise. This critical review describes the state-of-the-art development in the design, synthesis, characterisation, and application of the crystalline porous COF materials. Our own opinions on further development of the COF materials are also presented for discussion (155 references).
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Citations
Recent developments in copper-based, non-noble metal electrocatalysts for the oxygen reduction reaction
Cheng Du,Xiaohui Gao,Wei Chen +2 more
TL;DR: In this article, a review of the state of the art in the field of oxygen reduction reaction (ORR) catalysts is presented, which mainly focuses on recent research progress with Cu-based ORR catalysts and aims to aid readers' understanding of the status of development.
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Exploring Applications of Covalent Organic Frameworks: Homogeneous Reticulation of Radicals for Dynamic Nuclear Polarization
Wei Cao,Wei David Wang,Hai-Sen Xu,Ivan V. Sergeyev,Jochem Struppe,Xiaoling Wang,Frederic Mentink-Vigier,Zhehong Gan,Ming-Xing Xiao,Lu-Yao Wang,Guo-Peng Chen,San-Yuan Ding,Shi Bai,Wei Wang +13 more
TL;DR: This contribution not only realizes the direct construction of radical COFs from radical monomers, but also explores the new application of COFs as DNP polarizing agents.
Two-dimensional dual-pore covalent organic frameworks obtained from the combination of two D2h symmetrical building blocks
TL;DR: A strategy to construct covalent organic frameworks bearing two different kinds of pores has been developed, by which two dual-pore COFs were fabricated through the condensation reactions of two D2h symmetrical building blocks.
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Progress in Hybridization of Covalent Organic Frameworks and Metal-Organic Frameworks.
Yang Deng,Yue Wang,Xiao Xiao,Brett Jacob Saucedo,Zhijun Zhu,Ming-Li Xie,Xin Lin Xu,Kun Yao,Yanling Zhai,Zhen Zhang,Jun Chen +10 more
TL;DR: A comprehensive review of MOF/COF hybrid materials can be found in this paper , which summarizes the latest achievements and advancements in the design and synthesis of MOFs/COFs hybrid materials, including COFs covalently bonded to the surface functional groups of MoFs, MOFs grown on the surface of COFs, and their various applications in catalysis, energy storage, pollutant adsorption, gas separation, chemical sensing and biomedicine.
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References
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Hydrogen-storage materials for mobile applications
TL;DR: Recent developments in the search for innovative materials with high hydrogen-storage capacity are presented.
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.
Porous, Crystalline, Covalent Organic Frameworks
Adrien P. Côté,Annabelle I. Benin,Nathan W. Ockwig,Michael O'Keeffe,Adam J. Matzger,Omar M. Yaghi +5 more
TL;DR: Covalent organic frameworks (COFs) have been designed and successfully synthesized by condensation reactions of phenyl diboronic acid and hexahydroxytriphenylene to form rigid porous architectures with pore sizes ranging from 7 to 27 angstroms.
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