Journal Article10.1016/0167-5729(87)90007-0
Core-level binding-energy shifts at surfaces and in solids
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TL;DR: A review of core-level binding energy shifts observed in photoelectron spectroscopy can be found in this paper, where the authors focus on shifts since most of the chemical and physical insights provided by core levels are derived not from the core energies themselves but from shifts they exhibit.
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About: This article is published in Surface Science Reports. The article was published on 01 May 1987.
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Citations
A photoemission study of Pd ultrathin films on Pt (111).
TL;DR: The origin of surface core-level shift (SCLS) of Pd thin films on Pt (111) substrate is investigated and the VB spectrum shows a clear band narrowing, that is, the origin of the negative SCLS at monolayer coverage.
An XPS study of Mg overlayers on a Mo(100) surface
TL;DR: In this paper, the core-level binding energies of the atoms in a monolayer, a multilayer and a single-crystal surface layer are explained in terms of the coordination number and the charge transfer at the Mg/Mo interfaces.
15
The electronic structure of the aqueous permanganate ion: aqueous-phase energetics and molecular bonding studied using liquid jet photoelectron spectroscopy.
TL;DR: This work identified intermolecular coulombic decay relaxation processes following resonant X-ray excitation of the solute that highlight valence MnO4-(aq.)-H2O(l) electronic couplings and mapped the aqueous-phase electronic structure of this widely applied aQueous transition-metal complex ion.
Surface-bulk core-level binding-energy shifts for Al(100).
TL;DR: The mechanisms responsible for the core-level binding-energy shifts that occur for surface and bulk atoms of the Al(100) surface are identified and characterized through theoretical analyses of the surface electronic structure and can be resolved by present-day high-resolution photoemission measurements.
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XPS characterisation of the interface between anode and electrolyte in a proton conducting solid oxide fuel cell
Martin Fleissner Sunding,Demie Kepaptsoglou,Spyros Diplas,Spyros Diplas,Truls Norby,Anette Eleonora Gunnæs +5 more
TL;DR: In this paper, pulsed laser deposition nanometric layers of proton conducting calcium-doped lanthanum niobate (La 0.995 Ca 0.005 NbO 4 ) were deposited on nickel substrates in order to fabricate model structures of the electrolyte-anode interface present in potential proton-conducting solid oxide fuel cells (PC-SOFC).
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