Journal Article10.1016/S0079-6700(97)00031-2
Coordination polymerization of heterocyclic and heterounsaturated monomers
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TL;DR: In this paper, a review of coordination polymerization and copolymerization of heterocyclic and heterounsaturated monomers is presented in terms of the type of monomer, type of catalyst, structure of the active sites and polymerization mechanism.
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About: This article is published in Progress in Polymer Science. The article was published on 01 Sep 1998. The article focuses on the topics: Ring-opening polymerization & Coordination polymerization.
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Citations
Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?
TL;DR: This Review presents an overview of the available homogeneous catalytic routes that use carbon dioxide as a C(1) carbon source for the synthesis of industrial products as well as fine chemicals.
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Discrete Metal-Based Catalysts for the Copolymerization of CO2 and Epoxides: Discovery, Reactivity, Optimization, and Mechanism
TL;DR: Well-defined catalysts for epoxide-CO(2) copolymerization and related reactions are reviewed here.
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Supercritical and near-critical CO2 in green chemical synthesis and processing
TL;DR: A review of the use of CO 2 to create greener processes and products, with a focus on research and commercialization efforts performed since 1995, is presented in this article, which reveals that careful application of CO2 technology can result in products (and processes) that are cleaner, less expensive and of higher quality.
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Catalysts for CO2/epoxide copolymerisation
TL;DR: The article reviews recent developments (mostly since 2004 until June 2010) in catalysts for CO(2)/epoxide copolymerisation and in the properties of the polycarbonates.
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Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms
TL;DR: The catalytic copolymerization of CO 2 with epoxides has been known for over 40 years as mentioned in this paper, and although many heterogeneous and homogeneous catalyst systems have been developed, catalyst activity and selectivity still remain too low for large scale industrial application.
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References
Epoxide Polymerization and Copolymerization with Carbon Dioxide Using Diethylaluminum Chloride-25,27-Dimethoxy-26,28-dihydroxy-p-tert-butyl-Calix[4]arene System as a New Homogeneous Catalyst
TL;DR: In this paper, a substituted chelate phenolatoaluminum chloride, (25,27-dimethoxy-p-tert-butylcalix[4]arene-26,28-diolato) aluminum chloride, was derived from the reaction of diethyl aluminum chloride and 25,27 -dimethoxyl-hexyl-polymorphic polyethylene-polyethylene (DDPE) at reactants 1:1 mole ratio, which was applied successfully for the polymerization of propylene oxide and cyclohex
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Polymerization and copolymerization of β‐butyrolactone and benzyl‐β‐malolactonate by aluminoxane catalysts
Benvenuti Manuela,Robert W. Lenz +1 more
TL;DR: In this article, high molecular weight poly-β-hydroxybutyrate (PHB) and poly (β-HOG-co-βbenzyl malate) [P (HBBM) copolymers were obtained by ring-opening polymerization reactions of racemic β-butyrolactone (BL), using two types of oligomeric aluminoxane catalysts prepared by the reaction of water with either triethyl-aluminum or triisobutylaluminum (IBAO).
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Functional polycarbonate by copolymerization of carbon dioxide and epoxide: Synthesis and hydrolysis
TL;DR: In this article, a copolymerization of carbon dioxide and epoxides containing a carbonate substituent using the diethylzinc/water system as catalyst is described.
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Stereospecific polymerization of N‐carboxy‐DL alanine anhydride
TL;DR: Some organometallic systems were found to be effective as catalysts for the polymerization of N-carboxy-DL-alanine anhydride to give poly-α-alanin this paper.
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