Journal Article10.1021/IC301449Y
Complex open-framework germanate built by 8-coordinated Ge(10) clusters.
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TL;DR: Strong hydrogen bonding among the organic SDAs, water molecules, and Ge10 clusters resulted in helical networks in SU-67, a novel open-framework germanate synthesized under hydrothermal conditions using 2-methylpiperazine as the structure-directing agent (SDA).
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Abstract: A novel open-framework germanate [(C5H14N2)(2)(C5H12N2)(0.5)(H2O)(2.5)][Ge12.5O26(OH)(2)] with three-dimensional 10- and 11-ring channels, denoted as SU-67, has been synthesized under hydrothermal ...
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Citations
SU-77: An Open-Framework Germanate Containing 12 × 10 × 10-Ring Channels Solved by Combining Rotation Electron Diffraction and Powder X-ray Diffraction
TL;DR: A novel open-framework germanate, denoted as SU-77, was prepared by hydrothermal synthesis using ethylenediamine as the structure directing agent.
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SU-79: a novel germanate with 3D 10- and 11-ring channels templated by a square-planar nickel complex
Shiliang Huang,Shiliang Huang,Jie Su,Kirsten E. Christensen,A. Ken Inge,Jie Liang,Xiaodong Zou,Junliang Sun,Junliang Sun +8 more
TL;DR: An open-framework germanate denoted as SU-79 with the chemical formula [Ge12.5O26(OH)(2)]-[Ni(C3N2H10)(2 )](1.1)(NH4)(0.8)(C3n2H12)(0,5)(C 3n2h10)(1.5)(H2O)(2) has been synthesized under hydro/solvot.
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Interrupted silicogermanate with 10-ring channels: synthesis and structure determination by combining rotation electron diffraction and powder X-ray diffraction
TL;DR: Silicogermanate (JU110) with an interrupted open-framework has been synthesized by using a hydrothermal method using 1,1′-(1,4-phenylenebis(methylene))bis(1-methylpyrrolidin-1-ium) hydroxide as an organic structure-directing agent as mentioned in this paper.
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Two Unprecedented Germanoniobate Frameworks Based on High-Nuclearity Peanut-Shaped {Ge12Nb38} Clusters.
Yong-Jiang Wang,Lan Yu,Xinxiong Li,Yan-Qiong Sun,Shou-Tian Zheng +4 more
TL;DR: Two unprecedented germanoniobate frameworks based on high-nuclearity peanut-shaped {Ge12Nb38} clusters exhibit proton conduction and water vapor adsorption properties.
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Complex Open‐Framework Germanate Built by 8‐Coordinated Ge10 Clusters.
TL;DR: In this article, a new compound with three-dimensional 10-and 11-ring channels was synthesized from mixtures of GeO2, 2-methylpiperazine, and H2O (autoclave, 160 °C, 7 d).
References
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