Complete multinuclear solid‐state NMR of metal‐organic frameworks: The case of α‐Mg‐formate

TL;DR: The synthesis of the indium-based framework in methanol demonstrates a simple route to introduce porous hydrophobicity into a MIL-53-type framework by incorporation of metal-bridging -OCH3 groups in the MOF pores.

TL;DR: In this paper, a D2-responsive third sorption step was revealed, and a noticeable difference was observed in the uptakes of D2 and H2, which may have resulted from the additional space created for D2 due to its dense packing.

TL;DR: In this article, a general introduction to the field, typical aspects of certain MOFs and certain adsorbed molecules will be discussed and the combination with calculations and different experimental approaches are also discussed.

TL;DR: A comparative study shows that carbon monoxide (CO) adsorption does not induce framework shrinkage at high temperatures, suggesting that the NTE effect is guest-specific.

TL;DR: The Commission on Isotopic Abundances and Atomic Weights (CIAAW) of the International Union of Pure and Applied Chemistry (IUPAC) completed its last update of the isotopic compositions of the elements as determined by isotope-ratio mass spectrometry in 2009 as discussed by the authors.

TL;DR: In this article, the authors show that CO2 emissions track the high end of the latest generation of emissions scenarios, due to lower than anticipated carbon intensity improvements of emerging economies and higher global gross domestic product growth.

TL;DR: A review of metal organic frameworks (MOFs) can be found in this paper, where the authors introduce newcomers in chemical engineering discipline to the rapidly expanding MOF research works, and present a brief introduction to the currently available MOFs synthesis methods.

TL;DR: In this paper, different methods used for the synthesis of metal organic frameworks, the relationship between structural features and hydrogen adsorption, the strategies for hydrogen uptake improvement as well as the molecular simulation.