Journal Article10.1016/J.CHROMA.2003.10.127
Chromatographic and spectroscopic methods for the determination of solvent properties of room temperature ionic liquids
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TL;DR: All evidence points to the ionic liquids as a unique class of polar solvents suitable for technical development, however, further work is needed to fill the gaps in the authors' knowledge of the relationship between ion structures and physicochemical properties.
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About: This article is published in Journal of Chromatography A. The article was published on 28 May 2004. The article focuses on the topics: Ionic liquid & Solvation.
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Citations
Ionic liquids and catalysis: Recent progress from knowledge to applications
TL;DR: In this paper, a survey on the latest most representative developments and progress concerning ionic liquids, from their fundamental properties to their applications in catalytic processes, is presented, highlighting their emerging use for biomass treatment and transformation.
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Ionic liquids in separations.
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References
Recovery of Organic Products from Ionic Liquids Using Supercritical Carbon Dioxide
TL;DR: In this article, the feasibility of using supercritical carbon dioxide, another environmentally benign solvent, for the separation of organic solutes from an ionic liquid was investigated, and the results showed that supercritical fluid extraction is a viable separation technique with the additional benefits of environmental sustainability and pure product recovery.
Linear solvation energy relations
TL;DR: In this paper, the free energies of transfer of tetraalkylammonium halide ion pairs and dissociated ions, rates of nucleophilic substitution reactions, the contrast in solvent effects of water (HBD) and dimethyl sulfoxide (non-HBD), partition coefficients of non-hBD solutes between solvent bilayers, and family relationships between proton transfer (and non-protonic Lewis acid) basicities and corresponding β values for monomer HBA.
566
Room temperature ionic liquid as a novel medium for liquid/liquid extraction of metal ions
TL;DR: In this paper, a typical room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate [C4mim][PF6], was used as an alternative solvent to study liquid/liquid extraction of heavy metal ions.
559
Efficient, halide free synthesis of new, low cost ionic liquids: 1,3-dialkylimidazolium salts containing methyl- and ethyl-sulfate anions
John D. Holbrey,W. Matthew Reichert,Richard P. Swatloski,Grant A. Broker,William R. Pitner,Kenneth R. Seddon,Robin D. Rogers +6 more
TL;DR: In this paper, a series of low-cost ionic liquids containing methyl and ethyl-sulfate anions can be easily and efficiently prepared under ambient conditions by the reaction of 1-alkylimidazoles with dimethyl sulfate and diethyl sulfate.
548
Industrial preparation of phosphonium ionic liquids
TL;DR: In this paper, the authors present an account of their research into ionic liquids from the perspective of a future, large-scale producer of ionic liquid for industrial applications, and broad comparisons are made to relevant imidazolium systems.
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