Journal Article10.5059/yukigoseikyokaishi.80.232
Charged π-Electronic Systems That Provide Assembled Structures
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About: This article is published in Journal of Synthetic Organic Chemistry Japan. The article was published on 01 Mar 2022.
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Citations
Studies on Tetracyanocyclopentadienides in Synthetic Organic Chemistry
Takeo Sakai
TL;DR: The synthesis and application studies of tetra- and pentacyanocyclopentadienides (TCCP and PCCP) are described. TCCP and PCCP are superacid conjugate bases that exhibit high lipophilicity and weakly basic nature. They were used in various applications including methanolysis, phase transfer reactions, and cyclization-3-aza-Cope-Mannich cascade.
References
Ionic Liquid Crystals: Versatile Materials.
TL;DR: The discussion is focused on low molar mass and dendrimeric thermotropic ionic mesogens, as well as selected metal-containing compounds (metallomesogens), but some references to polymeric and/or lyotropic ionIC liquid crystals and particularly to ionic liquids will also be provided.
707
Chemical-stimuli-controllable circularly polarized luminescence from anion-responsive π-conjugated molecules.
Hiromitsu Maeda,Yuya Bando,Konomi Shimomura,Ippei Yamada,Masanobu Naito,Masanobu Naito,Kazuyuki Nobusawa,Hiroyuki Tsumatori,Tsuyoshi Kawai +8 more
TL;DR: This work has reported the first example of chemical-stimuli-responsive CPL properties, where appropriate pyrrole β-substituents induce distorted receptor π-planes and give larger circularly polarized luminescence (CPL), which can be tuned by chemical stimuli (anions).
400
Bridge-dependent electron transfer in porphyrin-based donor-bridge-acceptor systems.
TL;DR: Photoinduced electron transfer in donor-bridge-acceptor systems with zinc porphyrin (or its pyridine complex) as the donor and gold(III) porphirin as the acceptor has been studied and an electronic coupling of 5-20 cm(-)(1) between the donors and acceptor is estimated.
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