Book Chapter10.1016/BS.AGRON.2014.10.005
Chapter One – Mineral–Organic Associations: Formation, Properties, and Relevance in Soil Environments
Markus Kleber,Karin Eusterhues,Marco Keiluweit,Christian Mikutta,Robert Mikutta,Peter S. Nico +5 more
1.2K
TL;DR: An overview of the current knowledge on mineral-organic associations can be found in this article, where the authors identify key questions and future research needs, as well as a survey of the existing research work.
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Abstract: Minerals and organic matter (OM) may form intricate associations via myriad interactions. In soils, the associations of OM with mineral surfaces are mainly investigated because of their role in determining the long-term retention of OM. OM “must decay in order to release the energy and nutrients that drive live processes all over the planet” ( Janzen, 2006 ). Thus, the processes and mechanisms that retain OM in soil are a central concern to very different branches of environmental research. An agronomist may want to synchronize periods of high nutrient and energy release with the growth stages of a crop. An environmental chemist may wish to either immobilize an organic soil contaminant or enhance its decomposition into less harmful metabolites, while climate scientists need to understand the processes that mediate the production of potent greenhouse gases from decomposing OM. Associations of OM with pedogenic minerals (henceforth termed mineral–organic associations (MOAs)) are known to be key controls in these and many other processes. Here we strive to present an overview of the current knowledge on MOAs and identify key questions and future research needs.
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Citations
Effect of bacterial cell addition on Fe(III) reduction and soil organic matter transformation in a farmland soil
TL;DR: In this article , a model dissimilatory Fe reducing bacterium, Geobacter sulfurreducens, was added in either live or dead form in order to enhance Fe(III) reduction in soil and evaluate the accompanying transformation of SOM.
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•Dissertation
Land use and carbon dynamics in woody ecosystems
Christopher Dean
- 01 Jan 2017
TL;DR: In this paper, the authors investigated the role of land use change in carbon emissions from logging and rangeland grazing in woody ecosystems and found that the half-lives of wood products need to be increased by nearly an order of magnitude to not lose nearly half the carbon of primary forests when they are converted to secondary forests on harvesting cycles.
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Modelling the physical states, element stoichiometries and residence times of topsoil organic matter
Edward Tipping,Edwin C. Rowe +1 more
Abstract: Soil organic matter (SOM) is a major ecosystem component, central to soil fertility, carbon balance and other soil functions. To advance SOM modelling, we devised a steady‐state model of topsoil SOM, with explicit descriptions of physical states and properties, and used it to simulate SOM concentration, carbon:nitrogen:phosphorus (C:N:P) stoichiometry, bulk density and radiocarbon content. The model classifies SOM by element stoichiometry (αSOM is poor in N and P, βSOM is rich), mean residence times (1–2000 years) and physical state (free, occluded, adsorbed, hypoxic). The most stable SOM is either βSOM preferentially adsorbed by mineral matter, or αSOM in strongly hypoxic zones. Soil properties were simulated for random combinations of plant litter input (amount and C:N:P stoichiometry), mineral sorption capacity, propensity for hypoxia, and bulk density of non‐adsorbed αSOM. To optimize model parameters, outputs from 5000 simulations were used to construct bivariate relations among soil variables, which were compared with those found in data for 835 survey sites, covering all common land uses. The bivariate relations, and patterns of data scatter, were reproduced, and also variations in soil radiocarbon with soil type, suggesting that apparent scatter in measured data might reflect SOM diversity. The temporal acquisition by soil of ‘bomb 14C’ could also be simulated. The steady‐state model is the basis for a dynamic version, suitable for simulating changes in SOM through time. It provides insight into the possible manipulation of soil organic carbon (SOC) sequestration; for example, increasing litter inputs might only increase moderately‐stable SOC pools, whereas encouraging the creation of βSOM by adsorption to mineral matter from deeper soil could lead to long‐term stabilization.
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