Book Chapter10.1016/S1871-1731(07)80003-0
Chapter 1 Synchrotron Radiation and its Use in Art, Archaeometry, and Cultural Heritage Studies
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TL;DR: In this paper, a discussion of synchrotron radiation and its properties, monochromators, detectors, and techniques such as infrared (IR) microscopy, soft X-ray spectroscopy; X-Ray diffraction; micro-X-ray diffraction and Xray fluorescence analysis.
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Abstract: Synchrotron radiation has become an increasingly important tool for research in the fields of art, archaeometry, and the conservation of objects of cultural heritage significance. Scientists using conventional laboratory techniques are finding that the fundamental characteristics of synchrotron radiation — high brightness, low divergence, and highly linear polarization — can be used to give information not readily available in the laboratory context. In the author's experience, experiments do not translate directly from the laboratory to the synchrotron radiation laboratory: there are subtle differences in the use of what seem to be similar experimental apparatus. To achieve the best results, the research scientist must be able to discuss his or her research aims meaningfully with beamline scientists. And to be able to do this, the research scientist must have an understanding of the properties of synchrotron radiation, and also the various techniques that are available at synchrotrons but are unavailable in the laboratory. The chapter includes a discussion of synchrotron radiation and its properties, monochromators, detectors, and techniques such as infrared (IR) microscopy; soft X-ray spectroscopy; X-ray diffraction; micro-X-ray diffraction and X-ray fluorescence analysis; X-ray absorption spectroscopy (XAS), including extended X-ray absorption fine structure (EXAFS) and X-ray absorption near edge structure (XANES), and X-ray tomography. The underlying principles of these techniques are discussed here. Later in this book, authors will address these techniques in more detail.
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Citations
Perspectives for antimicrobial nanomaterials in cultural heritage conservation
Isabel Franco-Castillo,Isabel Franco-Castillo,Lara Hierro,Lara Hierro,Jesús M. de la Fuente,Jesús M. de la Fuente,Andrés Seral-Ascaso,Andrés Seral-Ascaso,Scott G. Mitchell,Scott G. Mitchell +9 more
TL;DR: In this paper, an overview of the current trends in antimicrobial products used to protect heritage items from microbial colonization and prevent their deterioration is presented, highlighting the promising potential of various different nanomaterials, as well as points of concern and clear red flags from some emerging research.
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The Examination of Works of Art using in Situ XRF Line and Area Scans
Karen Trentelman,Michel Bouchard,Monica Ganio,Carole Namowicz,Catherine Schmidt Patterson,Marc Walton +5 more
TL;DR: In this paper, the authors used spatially resolved element distributions generated by in situ X-ray fluorescence (XRF) line and area scans to provide information about works of art which may not be obtainable from single spot spectra.
X-ray fluorescence in investigations of cultural relics and archaeological finds.
TL;DR: Various techniques used in XRF analyses of works of art are reviewed, the advantages and limitations of the method are summarised, and some typical examples of its use are presented.
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SR-XRD and SR-FTIR study of the alteration of silver foils in medieval paintings.
TL;DR: The results obtained suggest that atmospheric corrosion is the dominant mechanism, and therefore that the degree of corrosion of the metal foils is mainly related to the conservation state of the protecting coatings.
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Ancient materials specificities for their synchrotron examination and insights into their epistemological implications
TL;DR: The importance of the a posteriori framework of the study of heterogeneous materials considered in their historicity as structuring parameters of their study is discussed, and the relevance of trace analyses, those of majors and the dynamics between both endpoints are suggested.
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References
X-ray focusing with lobster-eye optics: a comparison of theory with experiment
Andrew G. Peele,Keith A. Nugent,Andrei Rode,K. Gabel,Martin Richardson,Richard R. Strack,Walter P. Siegmund +6 more
TL;DR: An experimental investigation and comparison with simulation of the x-ray focusing of a flat, square profile microchannel plate using x rays from a laser-produced plasma finds the focal structure to be consistent with theoretical expectations.
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Studying skin of an egyptian mummy by infrared microscopy
TL;DR: In this paper, the state of conservation/degradation of mummy human remains, can be inferred from their biochemical composition, as well as the secondary structures of proteins using infrared microscopy.
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X-ray Applications with Glass-Capillary Optics.
TL;DR: The authors propose that crystallography with protein crystals is feasible on a 50 mum or smaller scale using capillary optics along with a cold gas stream and precision rotation stages for computed tomography and high-pressure experiments at the Cornell High Energy Synchrotron Source.
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X‐Ray Interferometric Measurements of the Forward Scattering Amplitude for Lithium Fluoride
D. C. Creagh,M. Hart +1 more
TL;DR: The X-ray refractive index of lithium fluoride was measured to an accuracy of a few parts in 109 over the wavelength range from AgKβ1 (λ = 0.497058 A) to CuKα1(λ = 1.54053 A).
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Combined X-ray microbeam small-angle scattering and fibre diffraction experiments on single native cellulose fibres
TL;DR: In this article, the morphology of single native cellulose (flax) fibres was investigated by means of simultaneous small-angle scattering and fibre diffraction using an X-ray microbeam and the azimuthal hroadenings both of the equatorial smallangle scattering streak and of Bragg reflections are found to be due to a misalignment of the crystalline cellulose microfibrils with respect to the fibre axis.
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