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Changes in the electronic structure and properties of graphene induced by molecular charge-transfer
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TL;DR: In this paper, aniline and nitrobenzene have been shown to change the Raman spectrum and the electronic structure of graphene, prepared by the exfoliation of graphitic oxide.
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Abstract: Interaction with electron donor and acceptor molecules such as aniline and nitrobenzene brings about marked changes in the Raman spectrum and the electronic structure of graphene, prepared by the exfoliation of graphitic oxide.
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Citations
Improved Superiority by Covalently Binding Dye to Graphene for Hydrogen Evolution from Water under Visible-Light Irradiation
TL;DR: In this article, a novel nanohybrid composed of bipyridine ruthenium complex (Ru(bpy)2(py)Cl/G), covalently functionalized graphene, has been synthesized successfully via coordination of Ru(bbi)2Cl2 with pyridine with pyramids.
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Chemical integration of reduced graphene oxide sheets encapsulated ZnCo2O4 quantum dots achieving excellent capacity storage for lithium-ion batteries
TL;DR: In this paper, a hybrid QDs ZCO/rGO electrodes exhibit an excellent initial discharge capacity for rechargeable lithium-ion batteries with high rate stability and high cyclic stability.
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Functionalized graphene nanosheets with improved dispersion stability and superior paclitaxel loading capacity.
TL;DR: This study reports the attempt of improving dispersibility of reduced graphene oxide (rGO) through differential functionalization of carboxyl moieties with ethylene diamine (EDA) and folic acid (FA) using carbodimide chemistry, which could substantially minimize the incidence of disruptive protein-carrier interactions and thus inflate the biomedical potential of graphene materials.
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Computational Studies on Non-covalent Interactions of Carbon and Boron Fullerenes with Graphene
Arun K. Manna,Swapan K. Pati +1 more
TL;DR: Understanding of the non-covalent functionalisation of graphene with various fullerenes would promote experimentalists to explore these systems, for their possible applications in electronic and opto-electronic devices.
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Molecule-Induced Conformational Change in Boron Nitride Nanosheets with Enhanced Surface Adsorption
Qiran Cai,Aijun Du,Guoping Gao,Srikanth Mateti,Bruce C. C. Cowie,Dong Qian,Shuang Zhang,Yuerui Lu,Lan Fu,Takashi Taniguchi,Shaoming Huang,Ying Chen,Rodney S. Ruoff,Lu Hua Li +13 more
TL;DR: In this paper, the authors demonstrate theoretically and experimentally that atomically thin boron nitride (BN) nanosheets as an adsorbent experience conformational changes upon surface adorption of molecules, increasing adsorption energy and efficiency.
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Functionalization of Graphene: Covalent and Non-Covalent Approaches, Derivatives and Applications
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Functionalized Single Graphene Sheets Derived from Splitting Graphite Oxide
Hannes C. Schniepp,Je-Luen Li,Michael J. McAllister,Hiroaki Sai,Margarita Herrera-Alonso,Douglas H. Adamson,Robert K. Prud'homme,Roberto Car,Dudley A. Saville,Ilhan A. Aksay +9 more
TL;DR: The process yields a wrinkled sheet structure resulting from reaction sites involved in oxidation and reduction processes, and functionalized graphene produced by this method is electrically conducting.