Journal Article10.1021/JA00279A083
Catalytic asymmetric induction. Highly enantioselective addition of dialkylzincs to aldehydes
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About: This article is published in Journal of the American Chemical Society. The article was published on 01 Sep 1986. The article focuses on the topics: Addition reaction & Enantioselective synthesis.
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Citations
Unexpected efficiency of non‐C2‐symmetric bis(hydroxyamide)‐based zinc‐chelate catalysts
Esther M. Sánchez-Carnerero,Tomás de las Casas Engel,Beatriz Lora Maroto,Santiago de la Moya Cerero +3 more
TL;DR: The previously established assumption on the necessity of using C(2) -symmetric bis(hydrdoxyamides) to generate C( 2) -Symmetric zinc-chelate catalysts can be discarded and the possibilities for designing new ligands based on the interesting hydroxyl-amide functional grouping are expanded.
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Catalytic Enantioselective Addition of Dialkylzincs to Aldehydes Using (2S)‐(−)‐3‐exo‐(Dimethylamino)Isoborneol [(2S)‐DAIB]: (S)‐1‐Phenyl‐1‐Propanol
Masato Kitamura,Hiromasa Oka,Seiji Suga,Ryoji Noyori,David E. Kaelin,Stephen F. Martin,Gregory L. Beutner,Scott E. Denmark +7 more
TL;DR: (S)-1-Phenyl-1-propanol) as mentioned in this paper, 1-propositionion, 1-person, 1proposition, (S) 1-phenyl 1-position.
7
Immobilization of chiral amide derived from (1R,2S)-(−)-norephedrine over 3D nanoporous silica for the enantioselective addition of diethylzinc to aldehydes
Umesh Balakrishnan,Umesh Balakrishnan,Nallamuthu Ananthi,Sivan Velmathi,Mercy R. Benzigar,Siddulu Naidu Talapaneni,Salem S. Al-Deyab,Katsuhiko Ariga,Ajayan Vinu,Ajayan Vinu +9 more
TL;DR: In this paper, a chiral amide synthesized from (1R, 2S)-(-)-norephedrine has been successfully immobilized onto three dimensional Ia3d cubic nanoporous material.
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A Convenient Stereoselective Synthesis of (1R,2S,3R,4S)-3-(Neopentyloxy)isoborneol
TL;DR: In this paper, a convenient preparation of (1R,2S,3R,4S)-3-(neopentyloxy)isoborneol, a valuable chiral auxiliary, is described.
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Chiral diethanolamines and their lithium alcoholates as catalysts in the enantioselective alkylation of benzaldehyde by diethylzinc.
TL;DR: In this paper, the enantioselective alkylation of benzaldehyde by diethylzinc in the presence of catalytic amounts of bis-erythro diethanolamines and their lithium alcoholates was studied.
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