Journal Article10.1021/JA00279A083
Catalytic asymmetric induction. Highly enantioselective addition of dialkylzincs to aldehydes
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About: This article is published in Journal of the American Chemical Society. The article was published on 01 Sep 1986. The article focuses on the topics: Addition reaction & Enantioselective synthesis.
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Citations
1.07 Recent Advances in Organozinc Reagents
T. Hirose,K. Kodama +1 more
- 01 Jan 2014
TL;DR: Recent advances in the catalytic asymmetric addition reactions of organozinc reagents to the C X π bonds (X=O, N) are summarized together with some applications.
8
C2-symmetrical bis(camphorsulfonamides) as chiral ligands for enantioselective addition of diethylzinc to benzaldehyde
TL;DR: In this paper, the activity of chiral bis(sulfonamide) ligands derived from camphor in the addition of diethylzinc to benzaldehyde was determined.
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Chiral Aryl Pyridyl Alcohols as Enantioselective Catalysts in the Addition of Diethylzinc to Substituted Benzaldehydes
Tien-Chu Chang,Chinpiao Chen +1 more
TL;DR: In this paper, the enantioselective addition of diethylzinc to substituted benzaldehydes, to yield alcohols with the (S)-configuration with an enantiomeric excess that typically ranges from 19 to 86%.
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Synthesis and optical activity analysis of chiral titanium(IV) sec-butoxide and its group IV analogues
TL;DR: In this article, the complete series of chiral group IV sec -butoxides has been obtained by the treatment of M(NMe 2 ) 4 (M = Ti, Zr, Hf) with resolved (R )-(−)- or (S )-(+)-2-butanol.
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Syntheses of chiral β-amino α-perfluoroalkylpropanol derivatives
TL;DR: Chiral β-amino α-perfluoroalkylpropanol derivatives were synthesized from N -Boc- l -phenylalanine methyl ester by substitution of the methoxy group into the corresponding perfluoroalky chain, followed by reduction and deprotection.
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