Journal Article10.1002/CHIN.199728254
Catalytic Addition of C—H Bonds to Multiple Bonds
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About: This article is published in ChemInform. The article was published on 08 Jul 1997. The article focuses on the topics: Addition reaction.
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Citations
Catalytic addition of C-H bonds to multiple bonds with the aid of ruthenium complexes
TL;DR: In this article, RuH2(CO)(PPh3)3 has been found to catalyze the direct addition of ortho carbon-hydrogen bonds of aromatic ketones to olefins and acetylenes.
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Activation Reactions Of Ru-Catalyzed Arylic Or Olefinic C-H Bonds
Shichao Yu,Shengming Ma +1 more
TL;DR: Ru-catalyzed activation of arylic or olefinic C-H bonds enables high-selectivity, high-efficiency reactions, including C-H/olefin couplings, hydroacylation, and silylation, with wide applicability and potential as complementary methods to Friedel-Crafts reactions.
References
Catalytic addition of CH bonds to multiple bonds
TL;DR: In contrast to a number of examples of stoichiomemc reactions involving C-H bond cleavage by transition metal complexes, the use of this chemistry in practical catalytic reactions is still rare as mentioned in this paper.