Borylated Dibenzoborepin: Synthesis by Skeletal Rearrangement and Photochromism Based on Bora-Nazarov Cyclization

TL;DR: An overview of the progress in the molecular construction of four-coordinate organoboron compounds with an emphasis on their applications in OLEDs is provided.

TL;DR: Rhodamine B salicylaldehyde hydrazone metal complex was found to undergo intramolecular ring-open reactions upon UV irradiation, which led to a distinct color and fluorescence change both in solution and in solid matrix, and the thermal bleaching rate was tunable by using different metal ions, temperatures, solvents, and chemical substitutions.

TL;DR: The incorporation of boron into the core structure of fused polycyclic aromatics generates compounds with highly attractive properties that have recently received significant attention, and this feature article summarizes the recent key developments.

TL;DR: An efficient and straightforward approach is presented to achieve early examples of highly luminescent chiral systems ( P5NN and P5BN) and an interesting thermochromic shift of the emission over a wide range of temperature is afforded.

TL;DR: Casey Wade is a student at Texas A&M University, where he currently studies anion recognition using main group Lewis acids, and the capture of fluoride, especially in water, is a stimulating academic challenge because of the high hydration enthalpy of this anion.

TL;DR: The past decade has witnessed renewed interest and numerous unexpected discoveries in the area of main group organometallic chemistry, and unusual bonding modes have been uncovered and new materials have been developed and new applications are being pursued.

TL;DR: In this article, a short review of the optical properties of three-coordinate boron in the main chain of an organic molecule is presented, with a focus on its properties as an π-acceptor in conjugated organic molecules.

TL;DR: In this article, a minireview summarizes recent work on compounds with 3-and 4-coordinate boron as well as borons clusters, placing it in the context of prior studies by the research groups of Williams and Glowgowski, Kaim, Lequan, and Marder.