Boration of an α,β-enone using a diboron promoted by a copper(I)–phosphine mixture catalyst

TL;DR: In this article, a white crystalline solid benzene complex was prepared by a reaction of trifluoromethanesulfonate under argoxide suspension by using the reaction of Trifluoric acid under a suspension of argoxide.

TL;DR: The reactivity of 1,3-enyne MIDA boronates enables the facile synthesis of gem-difluoro MIDA boronates and novel furan-based heteroatom-rich boron-containing molecules.

TL;DR: In this article, a planar chiral N-heterocyclic carbenes that incorporate an iron sandwich complex into the NHC framework for use in organocatalytic and transition metal-catalyzed reactions are described.

TL;DR: In this paper , bis(catecholato)diboron (B2cat2) can be prepared by the reaction of catechol with commercially available tetrakis(dimethylamino)dibroron1,3 followed by treatment with anhydrous HCl to yield the desired product and dimethylamine hydrochloride (eq 1).

TL;DR: In this paper, the catalytic addition of bis(pinacolato)diboron (1) to Pt(PPh3)4 was shown to generate cis-Pt(BO2C2Me4)2(Pph3)2 (5), whose structure was fully characterized by multinuclear NMR spectroscopy and single-crystal X-ray diffraction analysis.