Journal Article10.1016/S0040-4039(00)01161-8
Boration of an α,β-enone using a diboron promoted by a copper(I)–phosphine mixture catalyst
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TL;DR: In this article, the Cu(I)-catalyzed boration of an α,β-enone using a diboron is described, where the combination of a Cu(1) salt and tributylphosphine is an effective catalyst system.
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About: This article is published in Tetrahedron Letters. The article was published on 01 Aug 2000. The article focuses on the topics: Tributylphosphine & Enone.
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Citations
Transition-metal-catalyzed asymmetric defluorinative reactions
TL;DR: In this paper , the latest achievements in transition-metal-catalyzed enantioselective defluorinative coupling reactions have been comprehensively summarized on the basis of the classification of transition metal catalysts.
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Copper-catalyzed Borylation of Primary and Secondary Alkyl Halides with Bis(neopentyl glycolate) Diboron at Room Temperature
TL;DR: Borylation reactions are heavily dependent on diboron agents, whose structures prescribe the reaction conditions as mentioned in this paper, which necessitates extended investigation of borylation reaction using other dibore agents.
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Preparation of Modified Chitosan Microsphere-Supported Copper Catalysts for the Borylation of α,β-Unsaturated Compounds.
Wang Wei,Zufeng Xiao,Huang Chaofan,Zheng Kewang,Yin Luo,Yumin Dong,Zitong Shen,Li Wei,Caiqin Qin +8 more
TL;DR: Under mild conditions, such as no ligand at room temperature, the catalyst was successfully applied to catalyze the borylation of α,β-unsaturated receptors in a water-methanol medium, yielding 17%–100% of the corresponding β-hydroxy product.
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Robust dicopper(i) μ-boryl complexes supported by a dinucleating naphthyridine-based ligand
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References
Platinum(0)-catalyzed diboration of alkynes
TL;DR: In this paper, the first syn-selective addition of tetraalkoxydiboron 1 to alkenes was reported, which was efficiently catalyzed by the platinum(0) complex.
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Platinum(0)-Catalyzed Diboration of Alkynes with Tetrakis(alkoxo)diborons: An Efficient and Convenient Approach to cis-Bis(boryl)alkenes
TL;DR: In this paper, the catalytic addition of bis(pinacolato)diboron (1) to Pt(PPh3)4 was shown to generate cis-Pt(BO2C2Me4)2(Pph3)2 (5), whose structure was fully characterized by multinuclear NMR spectroscopy and single-crystal X-ray diffraction analysis.
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