Journal Article10.1016/S0040-4039(00)01161-8
Boration of an α,β-enone using a diboron promoted by a copper(I)–phosphine mixture catalyst
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TL;DR: In this article, the Cu(I)-catalyzed boration of an α,β-enone using a diboron is described, where the combination of a Cu(1) salt and tributylphosphine is an effective catalyst system.
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About: This article is published in Tetrahedron Letters. The article was published on 01 Aug 2000. The article focuses on the topics: Tributylphosphine & Enone.
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Citations
1,1-Diboration of Isocyanides with [2]Borametalloarenophanes
TL;DR: A series of new [3]diboracarbametallo-arenophanes was synthesized by reaction of [2]borametalaroenophanes or [3]-diboraplatinametallarhenophanes with isocyanides and was fully characterized by multi-scale characterization as mentioned in this paper.
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Copper(I) complexes of N-alkyl-substituted N-Heterocyclic carbenes
TL;DR: In this article, the synthesis and structural characterization of a variety of copper complexes bearing small alkyl-substituted N-heterocyclic carbene (NHC) ligands were reported.
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Synthesis of a bicyclic diborane by selective boron carbon bond formation
TL;DR: The bicyclic diboron species was generated with high selectivity by a combination of boron carbon bond formation and hydrogen iodide elimination events by X-ray diffraction, NMR spectroscopy and density functional theory calculations.
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Facile Transformation of α,β-Unsaturated Carboxylic Acids to Alkenylboronic Esters via Rhodium-catalyzed Decarbonylative Borylation of α,β-Unsaturated Thioesters
TL;DR: A two-step transformation of α,β-unsaturated carboxylic acids to alkenylboronic esters has been achieved via thioesterification of carboxYlic acids followed by rhodium-catalyzed decarbonylative borylation of thioesters.
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Tetra(pyrrolidino)diborane(4), [(C4H8N)2B]2, as a New Improved Alternative Synthetic Route to Bis(pinacolato)diborane(4) − Crystal Structures of the Intermediates
TL;DR: In this article, the crystal structure of tetra(pyrrolidino)diborane (4) (3) and its precursor, tris(pinacolato)borane, 1, were determined and the solvolysis reactions and solution behavior of 3 with alcohols were examined.
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References
Platinum(0)-catalyzed diboration of alkynes
TL;DR: In this paper, the first syn-selective addition of tetraalkoxydiboron 1 to alkenes was reported, which was efficiently catalyzed by the platinum(0) complex.
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Platinum(0)-Catalyzed Diboration of Alkynes with Tetrakis(alkoxo)diborons: An Efficient and Convenient Approach to cis-Bis(boryl)alkenes
TL;DR: In this paper, the catalytic addition of bis(pinacolato)diboron (1) to Pt(PPh3)4 was shown to generate cis-Pt(BO2C2Me4)2(Pph3)2 (5), whose structure was fully characterized by multinuclear NMR spectroscopy and single-crystal X-ray diffraction analysis.
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