Journal Article10.1016/S0040-4039(00)01161-8
Boration of an α,β-enone using a diboron promoted by a copper(I)–phosphine mixture catalyst
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TL;DR: In this article, the Cu(I)-catalyzed boration of an α,β-enone using a diboron is described, where the combination of a Cu(1) salt and tributylphosphine is an effective catalyst system.
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About: This article is published in Tetrahedron Letters. The article was published on 01 Aug 2000. The article focuses on the topics: Tributylphosphine & Enone.
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Citations
Enantio- and diastereoselective conjugate borylation/Mannich cyclization.
TL;DR: A mild and stereoselective copper-catalyzed conjugate borylation/Mannich cyclization reaction is reported, feasible with a broad range of Michael acceptors, and can be leveraged to generate versatile borylated tetrahydroquinoline scaffolds bearing three contiguous stereocenters.
Facile insertion of a cyclic alkyl(amino) carbene carbon into the B–B bond of diboron(4) reagents
TL;DR: The room temperature insertion of the carbene carbon atom of the cyclic (alkyl)(amino) carbene cAACMe into the B-B single bonds of the diboron(4) compounds B2pin2, B2cat2,B2neop2, and B2eg2 is reported.
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Copper(I)-Catalyzed Enantioselective Synthesis of α-Chiral Linear or Carbocyclic (E)-(γ-Alkoxyallyl)boronates.
TL;DR: In this paper, the title reaction starts from allyl acetates bearing a variety of functional groups and proceeds with high E-selectivity and excellent enantioselectivity, achieving a state-of-the-art performance.
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References
Platinum(0)-catalyzed diboration of alkynes
TL;DR: In this paper, the first syn-selective addition of tetraalkoxydiboron 1 to alkenes was reported, which was efficiently catalyzed by the platinum(0) complex.
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Platinum(0)-Catalyzed Diboration of Alkynes with Tetrakis(alkoxo)diborons: An Efficient and Convenient Approach to cis-Bis(boryl)alkenes
TL;DR: In this paper, the catalytic addition of bis(pinacolato)diboron (1) to Pt(PPh3)4 was shown to generate cis-Pt(BO2C2Me4)2(Pph3)2 (5), whose structure was fully characterized by multinuclear NMR spectroscopy and single-crystal X-ray diffraction analysis.
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