Journal Article10.1021/AR00178A005
BINAP: an efficient chiral element for asymmetric catalysis
Ryoji Noyori,Hidemasa Takaya +1 more
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About: This article is published in Accounts of Chemical Research. The article was published on 01 Oct 1990. The article focuses on the topics: BINAP & Enantioselective synthesis.
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Citations
Enantioselective Chemo- and Biocatalysis: Partners in Retrosynthesis.
TL;DR: The review provides a guide to the use of biocatalytic methods in the area of chemical synthesis with focused attention on retrosynthetic considerations and analysis and is expected to lead to better understanding of the characteristics and distinctions of the two complementary approaches.
253
Catalysis using multifunctional organosiliceous hybrid materials.
TL;DR: This paper will show how the different active sites in the framework can act in a synergistic or in a consecutive way following a similar functionality model to biological multisite catalysts.
249
Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki-Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations
TL;DR: In this article, the Suzuki−Miyaura process with Pd(OAc)2 and KenPhos as ligand was used to synthesize axially chiral biaryl amides.
248
Atroposelective Synthesis of Axially Chiral Biaryldiols via Organocatalytic Arylation of 2-Naphthols.
TL;DR: The first phosphoric acid-catalyzed asymmetric direct arylative reactions of 2-naphthols with quinone derivatives have been developed, providing efficient access to a class of axially chiral biaryldiols in good yields with excellent enantioselectivities under mild reaction conditions.
246
Synthesis of chiral bisphosphines with tunable bite angles and their applications in asymmetric hydrogenation of beta-ketoesters.
TL;DR: A strategy to restrict sp2-sp2 rotation in chiral biaryl ligands such as BINAP,2 BIPHEMP,3 and MeO-BIPHEP3 will be useful in generating new chiral ligands with tunable bite angles and the correlation of bite angles of chiral chelating phosphines with the enantioselectivity of a reaction may provide significant insights for future ligand design.
238
References
Synthesis of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP), an atropisomeric chiral bis(triaryl)phosphine, and its use in the rhodium(I)-catalyzed asymmetric hydrogenation of .alpha.-(acylamino)acrylic acids
961
Stereoselective hydrogenation via dynamic kinetic resolution
Ryoji Noyori,T. Ikeda,Takeshi Ohkuma,M. Widhalm,Masato Kitamura,Hidemasa Takaya,Susumu Akutagawa,Noboru Sayo,Takao Saito,T. Taketomi,Hidenori Kumobayashi +10 more
TL;DR: Stereoselectivite dans l'hydrogenation de cetoesters and d'un aminoester conjugue, catalysee par des complexes du ruthenium.
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