Journal Article10.1016/J.CCR.2020.213296
Asymmetric kinetic resolution polymerization
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TL;DR: A review of the literature related to the use of chiral metal complexes, organocatalysts and enzymes as promoters of asymmetric kinetic resolution polymerization (AKRP) can be found in this paper.
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About: This article is published in Coordination Chemistry Reviews. The article was published on 01 Jul 2020. The article focuses on the topics: Kinetic resolution & Enantioselective synthesis.
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Citations
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Advancing the Development of Recyclable Aromatic Polyesters by Functionalization and Stereocomplexation.
TL;DR: In this paper , a class of aromatic cyclic esters (M1 - M5 ) from thiosalicylic acid and epoxides was synthesized by facile one-pot synthesis.
70
Recent advances in enantioselective ring-opening polymerization and copolymerization
Xiaoyu Xie,Ziyu Huo,Eungyo Jang,Rong Tong +3 more
TL;DR: Recent advances in enantioselective ring-opening polymerization and copolymerization enable the synthesis of stereoregular, degradable polymers with improved properties, using homogeneous enantioselective catalysts, offering a sustainable alternative to petrochemical-based polyolefins.
22
Reaching High Stereoselectivity and Activity in Organocatalyzed Ring-Opening Polymerization of Racemic Lactide by the Combined Use of a Chiral (Thio)Urea and a N-Heterocyclic Carbene.
TL;DR: In this paper , a commercially available chiral thiourea (TU1), or its urea homologue (U1) can be used in conjunction with an appropriately selected N-heterocyclic carbene (NHC) to trigger the stereoselective ring-opening polymerization (ROP) of racemic lactide (rac-LA) at room temperature in toluene.
References
Supramolecular Helical Systems: Helical Assemblies of Small Molecules, Foldamers, and Polymers with Chiral Amplification and Their Functions
TL;DR: The recent advances in supramolecular helical assemblies formed from chiral and achiral small molecules, oligomers (foldamers), and helical and nonhelical polymers from the viewpoints of their formations with unique chiral phenomena, such as amplification of chirality during the dynamic helically assembled processes, properties, and specific functionalities.
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